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catena-Poly[[[aqua(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4) N,O (2):O (3),O (3′)] dihydrate]
The title complex, {[Cd(C(7)H(3)NO(4))(C(12)H(8)N(2))(H(2)O)]·2H(2)O}(n), is a one-dimensional coordination polymer, wherein the Cd atom is seven-coordinated by two 1,10-phenanthroline N atoms, one N and three O atoms from two different pyridine-2,3-dicarboxylate ligands, and one water molecule. I...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959933/ https://www.ncbi.nlm.nih.gov/pubmed/21581164 http://dx.doi.org/10.1107/S1600536808037203 |
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author | Li, Ming Ha, Wuzu Chang, Liang Yuan, Liangjie |
author_facet | Li, Ming Ha, Wuzu Chang, Liang Yuan, Liangjie |
author_sort | Li, Ming |
collection | PubMed |
description | The title complex, {[Cd(C(7)H(3)NO(4))(C(12)H(8)N(2))(H(2)O)]·2H(2)O}(n), is a one-dimensional coordination polymer, wherein the Cd atom is seven-coordinated by two 1,10-phenanthroline N atoms, one N and three O atoms from two different pyridine-2,3-dicarboxylate ligands, and one water molecule. It is further extended to a two-dimensional layer structure by hydrogen bonds and π–π stacking interactions [centroid-centroid distances of 3.560 (2) and 3.666 (2) Å]. There is a C4 water chain in the structure whose repeat unit contains four water molecules with O⋯O distances in the range 2.748 (3)–2.795 (4) Å. One of the two H atoms of each water of hydration is statistically distributed over two positions with equal occupancy. |
format | Text |
id | pubmed-2959933 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29599332010-12-30 catena-Poly[[[aqua(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4) N,O (2):O (3),O (3′)] dihydrate] Li, Ming Ha, Wuzu Chang, Liang Yuan, Liangjie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, {[Cd(C(7)H(3)NO(4))(C(12)H(8)N(2))(H(2)O)]·2H(2)O}(n), is a one-dimensional coordination polymer, wherein the Cd atom is seven-coordinated by two 1,10-phenanthroline N atoms, one N and three O atoms from two different pyridine-2,3-dicarboxylate ligands, and one water molecule. It is further extended to a two-dimensional layer structure by hydrogen bonds and π–π stacking interactions [centroid-centroid distances of 3.560 (2) and 3.666 (2) Å]. There is a C4 water chain in the structure whose repeat unit contains four water molecules with O⋯O distances in the range 2.748 (3)–2.795 (4) Å. One of the two H atoms of each water of hydration is statistically distributed over two positions with equal occupancy. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959933/ /pubmed/21581164 http://dx.doi.org/10.1107/S1600536808037203 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Ming Ha, Wuzu Chang, Liang Yuan, Liangjie catena-Poly[[[aqua(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4) N,O (2):O (3),O (3′)] dihydrate] |
title |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4)
N,O
(2):O
(3),O
(3′)] dihydrate] |
title_full |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4)
N,O
(2):O
(3),O
(3′)] dihydrate] |
title_fullStr |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4)
N,O
(2):O
(3),O
(3′)] dihydrate] |
title_full_unstemmed |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4)
N,O
(2):O
(3),O
(3′)] dihydrate] |
title_short |
catena-Poly[[[aqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxylato-κ(4)
N,O
(2):O
(3),O
(3′)] dihydrate] |
title_sort | catena-poly[[[aqua(1,10-phenanthroline-κ(2)
n,n′)cadmium(ii)]-μ-pyridine-2,3-dicarboxylato-κ(4)
n,o
(2):o
(3),o
(3′)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959933/ https://www.ncbi.nlm.nih.gov/pubmed/21581164 http://dx.doi.org/10.1107/S1600536808037203 |
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