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catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate]

The title complex, {[Cd(C(7)H(3)NO(4))(C(12)H(8)N(2))(H(2)O)]·2H(2)O}(n), is a one-dimensional coordination polymer, wherein the Cd atom is seven-coordinated by two 1,10-phenanthroline N atoms, one N and three O atoms from two different pyridine-2,3-dicarboxyl­ate ligands, and one water mol­ecule. I...

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Detalles Bibliográficos
Autores principales: Li, Ming, Ha, Wuzu, Chang, Liang, Yuan, Liangjie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959933/
https://www.ncbi.nlm.nih.gov/pubmed/21581164
http://dx.doi.org/10.1107/S1600536808037203
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author Li, Ming
Ha, Wuzu
Chang, Liang
Yuan, Liangjie
author_facet Li, Ming
Ha, Wuzu
Chang, Liang
Yuan, Liangjie
author_sort Li, Ming
collection PubMed
description The title complex, {[Cd(C(7)H(3)NO(4))(C(12)H(8)N(2))(H(2)O)]·2H(2)O}(n), is a one-dimensional coordination polymer, wherein the Cd atom is seven-coordinated by two 1,10-phenanthroline N atoms, one N and three O atoms from two different pyridine-2,3-dicarboxyl­ate ligands, and one water mol­ecule. It is further extended to a two-dimensional layer structure by hydrogen bonds and π–π stacking inter­actions [centroid-centroid distances of 3.560 (2) and 3.666 (2) Å]. There is a C4 water chain in the structure whose repeat unit contains four water mol­ecules with O⋯O distances in the range 2.748 (3)–2.795 (4) Å. One of the two H atoms of each water of hydration is statistically distributed over two positions with equal occupancy.
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spelling pubmed-29599332010-12-30 catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate] Li, Ming Ha, Wuzu Chang, Liang Yuan, Liangjie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, {[Cd(C(7)H(3)NO(4))(C(12)H(8)N(2))(H(2)O)]·2H(2)O}(n), is a one-dimensional coordination polymer, wherein the Cd atom is seven-coordinated by two 1,10-phenanthroline N atoms, one N and three O atoms from two different pyridine-2,3-dicarboxyl­ate ligands, and one water mol­ecule. It is further extended to a two-dimensional layer structure by hydrogen bonds and π–π stacking inter­actions [centroid-centroid distances of 3.560 (2) and 3.666 (2) Å]. There is a C4 water chain in the structure whose repeat unit contains four water mol­ecules with O⋯O distances in the range 2.748 (3)–2.795 (4) Å. One of the two H atoms of each water of hydration is statistically distributed over two positions with equal occupancy. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959933/ /pubmed/21581164 http://dx.doi.org/10.1107/S1600536808037203 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ming
Ha, Wuzu
Chang, Liang
Yuan, Liangjie
catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate]
title catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate]
title_full catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate]
title_fullStr catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate]
title_full_unstemmed catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate]
title_short catena-Poly[[[aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) N,O (2):O (3),O (3′)] dihydrate]
title_sort catena-poly[[[aqua­(1,10-phenanthroline-κ(2) n,n′)cadmium(ii)]-μ-pyridine-2,3-dicarboxyl­ato-κ(4) n,o (2):o (3),o (3′)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959933/
https://www.ncbi.nlm.nih.gov/pubmed/21581164
http://dx.doi.org/10.1107/S1600536808037203
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