Tetra-n-butyl­ammonium bis­(1,1-dicyano­ethyl­ene-2,2-dithiol­ato)platinum(II)

In the title compound, (C(16)H(36)N)(2)[Pt(C(4)N(2)S(2))(2)], the Pt(II) center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano­ethyl­ene-2,2-dithiol­ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances...

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Detalles Bibliográficos
Autores principales: Kanganga, Nyasha, Mann, Kent R., Janzen, Daron E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959936/
https://www.ncbi.nlm.nih.gov/pubmed/21581162
http://dx.doi.org/10.1107/S1600536808036726
Descripción
Sumario:In the title compound, (C(16)H(36)N)(2)[Pt(C(4)N(2)S(2))(2)], the Pt(II) center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano­ethyl­ene-2,2-dithiol­ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.

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