1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate

The title Schiff base compound, C(13)H(16)N(3)O(+)·PF(6) (−), was derived from the condensation of 2-hydroxy­benaldehyde with the ionic liquid 1-(2-amino­ethyl)-3-methyl­imidazolium hexa­fluoro­phosphate in an ethanol solution. The asymmetric unit comprises one cation and two PF(6) (−) anions. The d...

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Detalles Bibliográficos
Autores principales: Li, Bin, Li, Yi-Qun, Cai, Yue-Peng, Zhou, Mei-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959942/
https://www.ncbi.nlm.nih.gov/pubmed/21581337
http://dx.doi.org/10.1107/S1600536808037124
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author Li, Bin
Li, Yi-Qun
Cai, Yue-Peng
Zhou, Mei-Yun
author_facet Li, Bin
Li, Yi-Qun
Cai, Yue-Peng
Zhou, Mei-Yun
author_sort Li, Bin
collection PubMed
description The title Schiff base compound, C(13)H(16)N(3)O(+)·PF(6) (−), was derived from the condensation of 2-hydroxy­benaldehyde with the ionic liquid 1-(2-amino­ethyl)-3-methyl­imidazolium hexa­fluoro­phosphate in an ethanol solution. The asymmetric unit comprises one cation and two PF(6) (−) anions. The dihedral angle between the aromatic and imidazole rings is 15.2 (2)°. An intra­molecular O—H⋯N hydrogen bond is found which generates an S(6) ring motif.
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spelling pubmed-29599422010-12-30 1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate Li, Bin Li, Yi-Qun Cai, Yue-Peng Zhou, Mei-Yun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(13)H(16)N(3)O(+)·PF(6) (−), was derived from the condensation of 2-hydroxy­benaldehyde with the ionic liquid 1-(2-amino­ethyl)-3-methyl­imidazolium hexa­fluoro­phosphate in an ethanol solution. The asymmetric unit comprises one cation and two PF(6) (−) anions. The dihedral angle between the aromatic and imidazole rings is 15.2 (2)°. An intra­molecular O—H⋯N hydrogen bond is found which generates an S(6) ring motif. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959942/ /pubmed/21581337 http://dx.doi.org/10.1107/S1600536808037124 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Bin
Li, Yi-Qun
Cai, Yue-Peng
Zhou, Mei-Yun
1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate
title 1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate
title_full 1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate
title_fullStr 1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate
title_full_unstemmed 1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate
title_short 1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate
title_sort 1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3h-imidazolium hexafluorophosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959942/
https://www.ncbi.nlm.nih.gov/pubmed/21581337
http://dx.doi.org/10.1107/S1600536808037124
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