Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]

In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni(2)(N(3))(4)(C(12)H(12)N(2))(2)], the Ni(II) atom is five-coordinated by two N atoms of the 5,5′-dimethyl-2,2′-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal–bipyramidal geometry. The Ni...

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Detalles Bibliográficos
Autor principal: Hou, Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959945/
https://www.ncbi.nlm.nih.gov/pubmed/21581175
http://dx.doi.org/10.1107/S1600536808037902
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author Hou, Jin
author_facet Hou, Jin
author_sort Hou, Jin
collection PubMed
description In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni(2)(N(3))(4)(C(12)H(12)N(2))(2)], the Ni(II) atom is five-coordinated by two N atoms of the 5,5′-dimethyl-2,2′-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal–bipyramidal geometry. The Ni⋯Ni distance is 3.2398 (12) Å.
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spelling pubmed-29599452010-12-30 Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)] Hou, Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni(2)(N(3))(4)(C(12)H(12)N(2))(2)], the Ni(II) atom is five-coordinated by two N atoms of the 5,5′-dimethyl-2,2′-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal–bipyramidal geometry. The Ni⋯Ni distance is 3.2398 (12) Å. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959945/ /pubmed/21581175 http://dx.doi.org/10.1107/S1600536808037902 Text en © Jin Hou 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hou, Jin
Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_full Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_fullStr Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_full_unstemmed Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_short Di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_sort di-μ(1,1)-azido-bis­[azido­(5,5′-dimethyl-2,2′-bipyridine)nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959945/
https://www.ncbi.nlm.nih.gov/pubmed/21581175
http://dx.doi.org/10.1107/S1600536808037902
work_keys_str_mv AT houjin dim11azidobisazido55dimethyl22bipyridinenickelii

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