Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II)

In the title mononuclear copper(II) complex, [Cu(C(14)H(9)N(2)O)(2)], the Cu(II) atom, situated on an inversion centre, shows a slightly distorted square-planar geometry and is coordinated by the N and O atoms from two deprotonated symmetry-related Schiff base ligands. The Cu—N and Cu—O bond lengths...

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Detalles Bibliográficos
Autores principales: Xia, Rong, Xu, Hai-Jun, Wang, Han
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959947/
https://www.ncbi.nlm.nih.gov/pubmed/21581153
http://dx.doi.org/10.1107/S160053680803417X
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author Xia, Rong
Xu, Hai-Jun
Wang, Han
author_facet Xia, Rong
Xu, Hai-Jun
Wang, Han
author_sort Xia, Rong
collection PubMed
description In the title mononuclear copper(II) complex, [Cu(C(14)H(9)N(2)O)(2)], the Cu(II) atom, situated on an inversion centre, shows a slightly distorted square-planar geometry and is coordinated by the N and O atoms from two deprotonated symmetry-related Schiff base ligands. The Cu—N and Cu—O bond lengths are 2.009 (2) and 1.888 (2) Å, respectively. The dihedral angle between the cyano­phenyl rings and phenolate rings is 42.28 (13)°.
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spelling pubmed-29599472010-12-30 Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II) Xia, Rong Xu, Hai-Jun Wang, Han Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear copper(II) complex, [Cu(C(14)H(9)N(2)O)(2)], the Cu(II) atom, situated on an inversion centre, shows a slightly distorted square-planar geometry and is coordinated by the N and O atoms from two deprotonated symmetry-related Schiff base ligands. The Cu—N and Cu—O bond lengths are 2.009 (2) and 1.888 (2) Å, respectively. The dihedral angle between the cyano­phenyl rings and phenolate rings is 42.28 (13)°. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959947/ /pubmed/21581153 http://dx.doi.org/10.1107/S160053680803417X Text en © Xia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xia, Rong
Xu, Hai-Jun
Wang, Han
Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II)
title Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II)
title_full Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II)
title_fullStr Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II)
title_full_unstemmed Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II)
title_short Bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(II)
title_sort bis{2-[(2-cyano­phen­yl)imino­meth­yl]phenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959947/
https://www.ncbi.nlm.nih.gov/pubmed/21581153
http://dx.doi.org/10.1107/S160053680803417X
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AT xuhaijun bis22cyanophenyliminomethylphenolatocopperii
AT wanghan bis22cyanophenyliminomethylphenolatocopperii

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