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Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II)
The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethylaminoethanol in acetonitrile, in air. The mol...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959949/ https://www.ncbi.nlm.nih.gov/pubmed/21581197 http://dx.doi.org/10.1107/S1600536808037793 |
Sumario: | The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethylaminoethanol in acetonitrile, in air. The molecule is centrosymmetric with two monodeprotonated N-(2-hydroxyethyl)-N-methylglycines coordinated to the metal in a tridentate mode, giving a bicyclic chelate with two distorted five-membered rings. The Cu(II) ion possesses a distorted octahedral geometry, with the N and the O atoms from the carboxylate groups in the equatorial plane. In the crystal structure, intermolecular O—H⋯O hydrogen-bonding interactions from the alkoxide functions of the ligand through the inversion centre form columns of molecules propagated along the a axis. |
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