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Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)

The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethyl­amino­ethanol in acetonitrile, in air. The mol...

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Detalles Bibliográficos
Autores principales: Buvaylo, Elena A., Kokozay, Volodymyr N., Vassilyeva, Olga Yu., Skelton, Brian W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959949/
https://www.ncbi.nlm.nih.gov/pubmed/21581197
http://dx.doi.org/10.1107/S1600536808037793
Descripción
Sumario:The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethyl­amino­ethanol in acetonitrile, in air. The mol­ecule is centrosymmetric with two monodeprotonated N-(2-hydroxy­ethyl)-N-methyl­glycines coordinated to the metal in a tridentate mode, giving a bicyclic chelate with two distorted five-membered rings. The Cu(II) ion possesses a distorted octa­hedral geometry, with the N and the O atoms from the carboxyl­ate groups in the equatorial plane. In the crystal structure, inter­molecular O—H⋯O hydrogen-bonding inter­actions from the alkoxide functions of the ligand through the inversion centre form columns of mol­ecules propagated along the a axis.