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Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)

The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethyl­amino­ethanol in acetonitrile, in air. The mol...

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Autores principales: Buvaylo, Elena A., Kokozay, Volodymyr N., Vassilyeva, Olga Yu., Skelton, Brian W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959949/
https://www.ncbi.nlm.nih.gov/pubmed/21581197
http://dx.doi.org/10.1107/S1600536808037793
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author Buvaylo, Elena A.
Kokozay, Volodymyr N.
Vassilyeva, Olga Yu.
Skelton, Brian W.
author_facet Buvaylo, Elena A.
Kokozay, Volodymyr N.
Vassilyeva, Olga Yu.
Skelton, Brian W.
author_sort Buvaylo, Elena A.
collection PubMed
description The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethyl­amino­ethanol in acetonitrile, in air. The mol­ecule is centrosymmetric with two monodeprotonated N-(2-hydroxy­ethyl)-N-methyl­glycines coordinated to the metal in a tridentate mode, giving a bicyclic chelate with two distorted five-membered rings. The Cu(II) ion possesses a distorted octa­hedral geometry, with the N and the O atoms from the carboxyl­ate groups in the equatorial plane. In the crystal structure, inter­molecular O—H⋯O hydrogen-bonding inter­actions from the alkoxide functions of the ligand through the inversion centre form columns of mol­ecules propagated along the a axis.
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spelling pubmed-29599492010-12-30 Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II) Buvaylo, Elena A. Kokozay, Volodymyr N. Vassilyeva, Olga Yu. Skelton, Brian W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethyl­amino­ethanol in acetonitrile, in air. The mol­ecule is centrosymmetric with two monodeprotonated N-(2-hydroxy­ethyl)-N-methyl­glycines coordinated to the metal in a tridentate mode, giving a bicyclic chelate with two distorted five-membered rings. The Cu(II) ion possesses a distorted octa­hedral geometry, with the N and the O atoms from the carboxyl­ate groups in the equatorial plane. In the crystal structure, inter­molecular O—H⋯O hydrogen-bonding inter­actions from the alkoxide functions of the ligand through the inversion centre form columns of mol­ecules propagated along the a axis. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959949/ /pubmed/21581197 http://dx.doi.org/10.1107/S1600536808037793 Text en © Buvaylo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Buvaylo, Elena A.
Kokozay, Volodymyr N.
Vassilyeva, Olga Yu.
Skelton, Brian W.
Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)
title Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)
title_full Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)
title_fullStr Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)
title_full_unstemmed Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)
title_short Bis[N-(2-hydroxy­ethyl)-N-methyl­glycinato]copper(II)
title_sort bis[n-(2-hydroxy­ethyl)-n-methyl­glycinato]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959949/
https://www.ncbi.nlm.nih.gov/pubmed/21581197
http://dx.doi.org/10.1107/S1600536808037793
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