Cargando…
Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II)
The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethylaminoethanol in acetonitrile, in air. The mol...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959949/ https://www.ncbi.nlm.nih.gov/pubmed/21581197 http://dx.doi.org/10.1107/S1600536808037793 |
_version_ | 1782188622274887680 |
---|---|
author | Buvaylo, Elena A. Kokozay, Volodymyr N. Vassilyeva, Olga Yu. Skelton, Brian W. |
author_facet | Buvaylo, Elena A. Kokozay, Volodymyr N. Vassilyeva, Olga Yu. Skelton, Brian W. |
author_sort | Buvaylo, Elena A. |
collection | PubMed |
description | The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethylaminoethanol in acetonitrile, in air. The molecule is centrosymmetric with two monodeprotonated N-(2-hydroxyethyl)-N-methylglycines coordinated to the metal in a tridentate mode, giving a bicyclic chelate with two distorted five-membered rings. The Cu(II) ion possesses a distorted octahedral geometry, with the N and the O atoms from the carboxylate groups in the equatorial plane. In the crystal structure, intermolecular O—H⋯O hydrogen-bonding interactions from the alkoxide functions of the ligand through the inversion centre form columns of molecules propagated along the a axis. |
format | Text |
id | pubmed-2959949 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29599492010-12-30 Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II) Buvaylo, Elena A. Kokozay, Volodymyr N. Vassilyeva, Olga Yu. Skelton, Brian W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(5)H(10)NO(3))(2)], was obtained unintentionally as the product of an attempted synthesis of a Cu/Cd mixed-metal mixed-anion complex using zerovalent copper, cadmium(II) oxide and two ammonium salts in the presence of 2-dimethylaminoethanol in acetonitrile, in air. The molecule is centrosymmetric with two monodeprotonated N-(2-hydroxyethyl)-N-methylglycines coordinated to the metal in a tridentate mode, giving a bicyclic chelate with two distorted five-membered rings. The Cu(II) ion possesses a distorted octahedral geometry, with the N and the O atoms from the carboxylate groups in the equatorial plane. In the crystal structure, intermolecular O—H⋯O hydrogen-bonding interactions from the alkoxide functions of the ligand through the inversion centre form columns of molecules propagated along the a axis. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959949/ /pubmed/21581197 http://dx.doi.org/10.1107/S1600536808037793 Text en © Buvaylo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Buvaylo, Elena A. Kokozay, Volodymyr N. Vassilyeva, Olga Yu. Skelton, Brian W. Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II) |
title | Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II) |
title_full | Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II) |
title_fullStr | Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II) |
title_full_unstemmed | Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II) |
title_short | Bis[N-(2-hydroxyethyl)-N-methylglycinato]copper(II) |
title_sort | bis[n-(2-hydroxyethyl)-n-methylglycinato]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959949/ https://www.ncbi.nlm.nih.gov/pubmed/21581197 http://dx.doi.org/10.1107/S1600536808037793 |
work_keys_str_mv | AT buvayloelenaa bisn2hydroxyethylnmethylglycinatocopperii AT kokozayvolodymyrn bisn2hydroxyethylnmethylglycinatocopperii AT vassilyevaolgayu bisn2hydroxyethylnmethylglycinatocopperii AT skeltonbrianw bisn2hydroxyethylnmethylglycinatocopperii |