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Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II)

In the title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the manganese(II) cation (site symmetry [Image: see text]) is hexa­coordinated by four O and two N atoms in a distorted trans-MnN(2)O(4) octa­hedral geometry. The four O atoms belonging to two 2,4-penta­nedionate anions lie in the equ...

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Detalles Bibliográficos
Autores principales: Liu, Ying, He, Qingpeng, Zhang, Xianxi, Xue, Zechun, Lv, Chunyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959951/
https://www.ncbi.nlm.nih.gov/pubmed/21581201
http://dx.doi.org/10.1107/S1600536808038440
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author Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
author_facet Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
author_sort Liu, Ying
collection PubMed
description In the title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the manganese(II) cation (site symmetry [Image: see text]) is hexa­coordinated by four O and two N atoms in a distorted trans-MnN(2)O(4) octa­hedral geometry. The four O atoms belonging to two 2,4-penta­nedionate anions lie in the equatorial plane and the two N atoms occupy the axial coordination sites.
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spelling pubmed-29599512010-12-30 Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II) Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the manganese(II) cation (site symmetry [Image: see text]) is hexa­coordinated by four O and two N atoms in a distorted trans-MnN(2)O(4) octa­hedral geometry. The four O atoms belonging to two 2,4-penta­nedionate anions lie in the equatorial plane and the two N atoms occupy the axial coordination sites. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959951/ /pubmed/21581201 http://dx.doi.org/10.1107/S1600536808038440 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II)
title Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II)
title_full Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II)
title_fullStr Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II)
title_full_unstemmed Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II)
title_short Bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(II)
title_sort bis[2,4-penta­nedionato(1−)]bis­[4,4,5,5-tetra­methyl­-2-(4-pyrid­yl)-imidazoline-1-oxyl 3-oxide]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959951/
https://www.ncbi.nlm.nih.gov/pubmed/21581201
http://dx.doi.org/10.1107/S1600536808038440
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