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Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II)
In the title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the manganese(II) cation (site symmetry [Image: see text]) is hexacoordinated by four O and two N atoms in a distorted trans-MnN(2)O(4) octahedral geometry. The four O atoms belonging to two 2,4-pentanedionate anions lie in the equ...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959951/ https://www.ncbi.nlm.nih.gov/pubmed/21581201 http://dx.doi.org/10.1107/S1600536808038440 |
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author | Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan |
author_facet | Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan |
author_sort | Liu, Ying |
collection | PubMed |
description | In the title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the manganese(II) cation (site symmetry [Image: see text]) is hexacoordinated by four O and two N atoms in a distorted trans-MnN(2)O(4) octahedral geometry. The four O atoms belonging to two 2,4-pentanedionate anions lie in the equatorial plane and the two N atoms occupy the axial coordination sites. |
format | Text |
id | pubmed-2959951 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29599512010-12-30 Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II) Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))], the manganese(II) cation (site symmetry [Image: see text]) is hexacoordinated by four O and two N atoms in a distorted trans-MnN(2)O(4) octahedral geometry. The four O atoms belonging to two 2,4-pentanedionate anions lie in the equatorial plane and the two N atoms occupy the axial coordination sites. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959951/ /pubmed/21581201 http://dx.doi.org/10.1107/S1600536808038440 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II) |
title | Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II) |
title_full | Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II) |
title_fullStr | Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II) |
title_full_unstemmed | Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II) |
title_short | Bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(II) |
title_sort | bis[2,4-pentanedionato(1−)]bis[4,4,5,5-tetramethyl-2-(4-pyridyl)-imidazoline-1-oxyl 3-oxide]manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959951/ https://www.ncbi.nlm.nih.gov/pubmed/21581201 http://dx.doi.org/10.1107/S1600536808038440 |
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