2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane

The title compound, C(24)H(56)N(4)P(6) or ((i)Pr(2)N)(2)P–P(4)–P(N(i)Pr(2))(2), adopts a butterfly structure, with planar environments for the N atoms and pyramidal environments for the P atoms. The structure studied has a 15% twin component that is related by a twofold rotation about [100].

Detalles Bibliográficos
Autores principales: Łapczuk-Krygier, Agnieszka, Baranowska, Katarzyna, Pikies, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959955/
https://www.ncbi.nlm.nih.gov/pubmed/21581395
http://dx.doi.org/10.1107/S1600536808037938
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author Łapczuk-Krygier, Agnieszka
Baranowska, Katarzyna
Pikies, Jerzy
author_facet Łapczuk-Krygier, Agnieszka
Baranowska, Katarzyna
Pikies, Jerzy
author_sort Łapczuk-Krygier, Agnieszka
collection PubMed
description The title compound, C(24)H(56)N(4)P(6) or ((i)Pr(2)N)(2)P–P(4)–P(N(i)Pr(2))(2), adopts a butterfly structure, with planar environments for the N atoms and pyramidal environments for the P atoms. The structure studied has a 15% twin component that is related by a twofold rotation about [100].
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spelling pubmed-29599552010-12-30 2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane Łapczuk-Krygier, Agnieszka Baranowska, Katarzyna Pikies, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(56)N(4)P(6) or ((i)Pr(2)N)(2)P–P(4)–P(N(i)Pr(2))(2), adopts a butterfly structure, with planar environments for the N atoms and pyramidal environments for the P atoms. The structure studied has a 15% twin component that is related by a twofold rotation about [100]. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959955/ /pubmed/21581395 http://dx.doi.org/10.1107/S1600536808037938 Text en © Łapczuk-Krygier et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Łapczuk-Krygier, Agnieszka
Baranowska, Katarzyna
Pikies, Jerzy
2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane
title 2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane
title_full 2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane
title_fullStr 2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane
title_full_unstemmed 2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane
title_short 2,4-Bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane
title_sort 2,4-bis[bis(diisopropyl­amino)­phos­phanyl]-1,2,3,4-tetra­phospha­bicyclo[1.1.0]butane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959955/
https://www.ncbi.nlm.nih.gov/pubmed/21581395
http://dx.doi.org/10.1107/S1600536808037938
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AT baranowskakatarzyna 24bisbisdiisopropylaminophosphanyl1234tetraphosphabicyclo110butane
AT pikiesjerzy 24bisbisdiisopropylaminophosphanyl1234tetraphosphabicyclo110butane

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