(Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)

In the title complex, [Cu(C(2)H(3)O(2))(C(10)H(8)N(2))(2)](CH(3)CH(2)OSO(3))(0.5)(CH(3)OSO(3))(0.5), the Cu(II) ion is bis-chelated by two 2,2′-bipyridine lignds and coordinated by an O atom of an acetate ligand in a CuN(4)O disorted square-pyramidal environment. In the structure, equal amounts of m...

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Detalles Bibliográficos
Autores principales: Wen, Zhi-Gang, Li, Mao-Lian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959956/
https://www.ncbi.nlm.nih.gov/pubmed/21581170
http://dx.doi.org/10.1107/S1600536808037331
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author Wen, Zhi-Gang
Li, Mao-Lian
author_facet Wen, Zhi-Gang
Li, Mao-Lian
author_sort Wen, Zhi-Gang
collection PubMed
description In the title complex, [Cu(C(2)H(3)O(2))(C(10)H(8)N(2))(2)](CH(3)CH(2)OSO(3))(0.5)(CH(3)OSO(3))(0.5), the Cu(II) ion is bis-chelated by two 2,2′-bipyridine lignds and coordinated by an O atom of an acetate ligand in a CuN(4)O disorted square-pyramidal environment. In the structure, equal amounts of methyl sulfate and ethyl sulfate anions are disordered on the same crystallographic sites. The crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions.
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spelling pubmed-29599562010-12-30 (Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5) Wen, Zhi-Gang Li, Mao-Lian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(2)H(3)O(2))(C(10)H(8)N(2))(2)](CH(3)CH(2)OSO(3))(0.5)(CH(3)OSO(3))(0.5), the Cu(II) ion is bis-chelated by two 2,2′-bipyridine lignds and coordinated by an O atom of an acetate ligand in a CuN(4)O disorted square-pyramidal environment. In the structure, equal amounts of methyl sulfate and ethyl sulfate anions are disordered on the same crystallographic sites. The crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959956/ /pubmed/21581170 http://dx.doi.org/10.1107/S1600536808037331 Text en © Wen and Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Zhi-Gang
Li, Mao-Lian
(Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)
title (Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)
title_full (Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)
title_fullStr (Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)
title_full_unstemmed (Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)
title_short (Acetato-κO)bis­(2,2′-bipyridyl-κ(2) N,N′)copper(II)–ethyl sulfate–methyl sulfate (1/0.5/0.5)
title_sort (acetato-κo)bis­(2,2′-bipyridyl-κ(2) n,n′)copper(ii)–ethyl sulfate–methyl sulfate (1/0.5/0.5)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959956/
https://www.ncbi.nlm.nih.gov/pubmed/21581170
http://dx.doi.org/10.1107/S1600536808037331
work_keys_str_mv AT wenzhigang acetatokobis22bipyridylk2nncopperiiethylsulfatemethylsulfate10505
AT limaolian acetatokobis22bipyridylk2nncopperiiethylsulfatemethylsulfate10505

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