Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]

In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl­pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa­hedral coordination geometry compr...

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Detalles Bibliográficos
Autores principales: Xia, HongYing, Liu, YueLong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959963/
https://www.ncbi.nlm.nih.gov/pubmed/21581124
http://dx.doi.org/10.1107/S1600536808035253
Descripción
Sumario:In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl­pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa­hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis­(3,5-dimethyl­pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra­hedral coordination geometry comprising four chloride anions.

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