Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]

In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl­pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa­hedral coordination geometry compr...

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Detalles Bibliográficos
Autores principales: Xia, HongYing, Liu, YueLong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959963/
https://www.ncbi.nlm.nih.gov/pubmed/21581124
http://dx.doi.org/10.1107/S1600536808035253
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author Xia, HongYing
Liu, YueLong
author_facet Xia, HongYing
Liu, YueLong
author_sort Xia, HongYing
collection PubMed
description In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl­pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa­hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis­(3,5-dimethyl­pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra­hedral coordination geometry comprising four chloride anions.
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spelling pubmed-29599632010-12-30 Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)] Xia, HongYing Liu, YueLong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl­pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa­hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis­(3,5-dimethyl­pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra­hedral coordination geometry comprising four chloride anions. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959963/ /pubmed/21581124 http://dx.doi.org/10.1107/S1600536808035253 Text en © Xia and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xia, HongYing
Liu, YueLong
Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]
title Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]
title_full Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]
title_fullStr Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]
title_full_unstemmed Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]
title_short Di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κN (2))methane]iron(II)} bis­[tetra­chloridoferrate(III)]
title_sort di-μ-chlorido-bis­{bis­[3,5-dimethyl­pyrazol-1-yl-κn (2))methane]iron(ii)} bis­[tetra­chloridoferrate(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959963/
https://www.ncbi.nlm.nih.gov/pubmed/21581124
http://dx.doi.org/10.1107/S1600536808035253
work_keys_str_mv AT xiahongying dimchloridobisbis35dimethylpyrazol1ylkn2methaneironiibistetrachloridoferrateiii
AT liuyuelong dimchloridobisbis35dimethylpyrazol1ylkn2methaneironiibistetrachloridoferrateiii

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