Cargando…

(S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene

The absolute configuration of the title compound, [Fe(C(5)H(5))(C(36)H(29)OP(2))], is S(p) at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intra­molecular C—H⋯P contact with an H⋯P distance of 2.56 Å. The hydr­oxy group is...

Descripción completa

Detalles Bibliográficos
Autores principales: Bats, Jan W., Doppiu, Angelino, Rivas Nass, Andreas, Hashmi, A. Stephen K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959966/
https://www.ncbi.nlm.nih.gov/pubmed/21581185
http://dx.doi.org/10.1107/S1600536808038294
Descripción
Sumario:The absolute configuration of the title compound, [Fe(C(5)H(5))(C(36)H(29)OP(2))], is S(p) at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intra­molecular C—H⋯P contact with an H⋯P distance of 2.56 Å. The hydr­oxy group is involved in an intra­molecular O—H⋯π(phen­yl) inter­action. The crystal packing shows five very weak inter­molecular C—H⋯π contacts, with H⋯Cg distances between 3.26 and 3.39 Å (Cg is the centroid of a phenyl or cyclo­penta­dienyl ring).