(S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene

The absolute configuration of the title compound, [Fe(C(5)H(5))(C(36)H(29)OP(2))], is S(p) at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intra­molecular C—H⋯P contact with an H⋯P distance of 2.56 Å. The hydr­oxy group is...

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Detalles Bibliográficos
Autores principales: Bats, Jan W., Doppiu, Angelino, Rivas Nass, Andreas, Hashmi, A. Stephen K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959966/
https://www.ncbi.nlm.nih.gov/pubmed/21581185
http://dx.doi.org/10.1107/S1600536808038294
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author Bats, Jan W.
Doppiu, Angelino
Rivas Nass, Andreas
Hashmi, A. Stephen K.
author_facet Bats, Jan W.
Doppiu, Angelino
Rivas Nass, Andreas
Hashmi, A. Stephen K.
author_sort Bats, Jan W.
collection PubMed
description The absolute configuration of the title compound, [Fe(C(5)H(5))(C(36)H(29)OP(2))], is S(p) at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intra­molecular C—H⋯P contact with an H⋯P distance of 2.56 Å. The hydr­oxy group is involved in an intra­molecular O—H⋯π(phen­yl) inter­action. The crystal packing shows five very weak inter­molecular C—H⋯π contacts, with H⋯Cg distances between 3.26 and 3.39 Å (Cg is the centroid of a phenyl or cyclo­penta­dienyl ring).
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spelling pubmed-29599662010-12-30 (S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene Bats, Jan W. Doppiu, Angelino Rivas Nass, Andreas Hashmi, A. Stephen K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The absolute configuration of the title compound, [Fe(C(5)H(5))(C(36)H(29)OP(2))], is S(p) at the ferrocene group and S at the asymmetric C atom. Both P atoms have a trigonal–pyramidal conformation. There is a short intra­molecular C—H⋯P contact with an H⋯P distance of 2.56 Å. The hydr­oxy group is involved in an intra­molecular O—H⋯π(phen­yl) inter­action. The crystal packing shows five very weak inter­molecular C—H⋯π contacts, with H⋯Cg distances between 3.26 and 3.39 Å (Cg is the centroid of a phenyl or cyclo­penta­dienyl ring). International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959966/ /pubmed/21581185 http://dx.doi.org/10.1107/S1600536808038294 Text en © Bats et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bats, Jan W.
Doppiu, Angelino
Rivas Nass, Andreas
Hashmi, A. Stephen K.
(S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene
title (S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene
title_full (S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene
title_fullStr (S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene
title_full_unstemmed (S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene
title_short (S(p))-1-Diphenyl­phosphanyl-2-{(S)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene
title_sort (s(p))-1-diphenyl­phosphanyl-2-{(s)-[2-(diphenyl­phosphan­yl)phen­yl]hydroxy­meth­yl}ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959966/
https://www.ncbi.nlm.nih.gov/pubmed/21581185
http://dx.doi.org/10.1107/S1600536808038294
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AT rivasnassandreas sp1diphenylphosphanyl2s2diphenylphosphanylphenylhydroxymethylferrocene
AT hashmiastephenk sp1diphenylphosphanyl2s2diphenylphosphanylphenylhydroxymethylferrocene

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