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Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4) O:O′:O′′:O′′′-tetravanadium(V)]]
In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n−) layers. These aggregate into the three-dimensional structure via N—H⋯O hydrogen-bonding mechanisms imparted by 4,4′-iminodipyridi...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959979/ https://www.ncbi.nlm.nih.gov/pubmed/21581199 http://dx.doi.org/10.1107/S1600536808038348 |
| _version_ | 1782188629541519360 |
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| author | Farnum, Gregory A. LaDuca, Robert L. |
| author_facet | Farnum, Gregory A. LaDuca, Robert L. |
| author_sort | Farnum, Gregory A. |
| collection | PubMed |
| description | In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n−) layers. These aggregate into the three-dimensional structure via N—H⋯O hydrogen-bonding mechanisms imparted by 4,4′-iminodipyridinium dications situated between the layers. |
| format | Text |
| id | pubmed-2959979 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29599792010-12-30 Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4) O:O′:O′′:O′′′-tetravanadium(V)]] Farnum, Gregory A. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, {(C(10)H(11)N(3))[V(4)O(8)(PO(4))(2)]}(n), cubane-like [V(4)O(8)](4+) clusters are connected by phosphate anions into anionic [V(4)P(2)O(16)](n) (2n−) layers. These aggregate into the three-dimensional structure via N—H⋯O hydrogen-bonding mechanisms imparted by 4,4′-iminodipyridinium dications situated between the layers. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959979/ /pubmed/21581199 http://dx.doi.org/10.1107/S1600536808038348 Text en © Farnum and LaDuca 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Farnum, Gregory A. LaDuca, Robert L. Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4) O:O′:O′′:O′′′-tetravanadium(V)]] |
| title | Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4)
O:O′:O′′:O′′′-tetravanadium(V)]] |
| title_full | Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4)
O:O′:O′′:O′′′-tetravanadium(V)]] |
| title_fullStr | Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4)
O:O′:O′′:O′′′-tetravanadium(V)]] |
| title_full_unstemmed | Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4)
O:O′:O′′:O′′′-tetravanadium(V)]] |
| title_short | Poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4)
O:O′:O′′:O′′′-tetravanadium(V)]] |
| title_sort | poly[4,4′-iminodipyridinium [tetra-μ(3)-oxido-tetraoxido-di-μ(4)-phosphato-κ(4)
o:o′:o′′:o′′′-tetravanadium(v)]] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959979/ https://www.ncbi.nlm.nih.gov/pubmed/21581199 http://dx.doi.org/10.1107/S1600536808038348 |
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