Redetermination of cis-diaqua­diglycolato­zinc(II)

The title complex, [Zn(C(2)H(3)O(3))(2)(H(2)O)(2)], was prepared and the crystal structure determined as part of a (67)Zn solid state nuclear magnetic resonance study. In the title complex, the Zn atom has a disorted octa­hedral coordination comprising two bidentate glycolate ligands and two water m...

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Detalles Bibliográficos
Autores principales: Kennedy, Paul, Francis, Neferterneken, Rovnyak, David, Kastner, Margaret E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959985/
https://www.ncbi.nlm.nih.gov/pubmed/21581224
http://dx.doi.org/10.1107/S1600536808039585
Descripción
Sumario:The title complex, [Zn(C(2)H(3)O(3))(2)(H(2)O)(2)], was prepared and the crystal structure determined as part of a (67)Zn solid state nuclear magnetic resonance study. In the title complex, the Zn atom has a disorted octa­hedral coordination comprising two bidentate glycolate ligands and two water mol­ecules. The water mol­ecules are cis to each other; one is trans to a carboxyl­ate O atom and the other trans to an alcohol O atom. The crystal structure has an extensive O—H⋯O hydrogen-bond network.

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