Redetermination of cis-diaqua­diglycolato­zinc(II)

The title complex, [Zn(C(2)H(3)O(3))(2)(H(2)O)(2)], was prepared and the crystal structure determined as part of a (67)Zn solid state nuclear magnetic resonance study. In the title complex, the Zn atom has a disorted octa­hedral coordination comprising two bidentate glycolate ligands and two water m...

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Autores principales: Kennedy, Paul, Francis, Neferterneken, Rovnyak, David, Kastner, Margaret E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959985/
https://www.ncbi.nlm.nih.gov/pubmed/21581224
http://dx.doi.org/10.1107/S1600536808039585
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author Kennedy, Paul
Francis, Neferterneken
Rovnyak, David
Kastner, Margaret E.
author_facet Kennedy, Paul
Francis, Neferterneken
Rovnyak, David
Kastner, Margaret E.
author_sort Kennedy, Paul
collection PubMed
description The title complex, [Zn(C(2)H(3)O(3))(2)(H(2)O)(2)], was prepared and the crystal structure determined as part of a (67)Zn solid state nuclear magnetic resonance study. In the title complex, the Zn atom has a disorted octa­hedral coordination comprising two bidentate glycolate ligands and two water mol­ecules. The water mol­ecules are cis to each other; one is trans to a carboxyl­ate O atom and the other trans to an alcohol O atom. The crystal structure has an extensive O—H⋯O hydrogen-bond network.
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spelling pubmed-29599852010-12-30 Redetermination of cis-diaqua­diglycolato­zinc(II) Kennedy, Paul Francis, Neferterneken Rovnyak, David Kastner, Margaret E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Zn(C(2)H(3)O(3))(2)(H(2)O)(2)], was prepared and the crystal structure determined as part of a (67)Zn solid state nuclear magnetic resonance study. In the title complex, the Zn atom has a disorted octa­hedral coordination comprising two bidentate glycolate ligands and two water mol­ecules. The water mol­ecules are cis to each other; one is trans to a carboxyl­ate O atom and the other trans to an alcohol O atom. The crystal structure has an extensive O—H⋯O hydrogen-bond network. International Union of Crystallography 2008-11-29 /pmc/articles/PMC2959985/ /pubmed/21581224 http://dx.doi.org/10.1107/S1600536808039585 Text en © Kennedy et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kennedy, Paul
Francis, Neferterneken
Rovnyak, David
Kastner, Margaret E.
Redetermination of cis-diaqua­diglycolato­zinc(II)
title Redetermination of cis-diaqua­diglycolato­zinc(II)
title_full Redetermination of cis-diaqua­diglycolato­zinc(II)
title_fullStr Redetermination of cis-diaqua­diglycolato­zinc(II)
title_full_unstemmed Redetermination of cis-diaqua­diglycolato­zinc(II)
title_short Redetermination of cis-diaqua­diglycolato­zinc(II)
title_sort redetermination of cis-diaqua­diglycolato­zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959985/
https://www.ncbi.nlm.nih.gov/pubmed/21581224
http://dx.doi.org/10.1107/S1600536808039585
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AT francisneferterneken redeterminationofcisdiaquadiglycolatozincii
AT rovnyakdavid redeterminationofcisdiaquadiglycolatozincii
AT kastnermargarete redeterminationofcisdiaquadiglycolatozincii

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