Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate

The title compound, [Co(C(10)H(8)N(2))(3)]Cl(3)·4H(2)O, contains discrete [Co(bpy)(3)](3+) cations (bpy is 2,2′-bipyridine), Cl(−) anions and water mol­ecules. The [Co(bpy)(3)](3+) complex cation exhibits C (2) symmetry with the twofold axis through the central Co atom and bis­ecting one bpy ligand...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Wen, Xu, Wei, Lin, Jian-Li, Xie, Hong-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959986/
https://www.ncbi.nlm.nih.gov/pubmed/21581186
http://dx.doi.org/10.1107/S1600536808038154
Descripción
Sumario:The title compound, [Co(C(10)H(8)N(2))(3)]Cl(3)·4H(2)O, contains discrete [Co(bpy)(3)](3+) cations (bpy is 2,2′-bipyridine), Cl(−) anions and water mol­ecules. The [Co(bpy)(3)](3+) complex cation exhibits C (2) symmetry with the twofold axis through the central Co atom and bis­ecting one bpy ligand and one of the Cl(−) anions. The four solvent water mol­ecules and the remaining two Cl(−) anions lie on a mirror plane. Hydrogen-bond inter­actions define a two-dimensional layer structure parallel to (100), which consists of seven-membered [Cl(2)(H(2)O)(5)], eight-membered [Cl(4)(H(2)O)(4)] and ten-membered [Cl(2)(H(2)O)(8)] rings.

Ejemplares similares