Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate

The title compound, [Co(C(10)H(8)N(2))(3)]Cl(3)·4H(2)O, contains discrete [Co(bpy)(3)](3+) cations (bpy is 2,2′-bipyridine), Cl(−) anions and water mol­ecules. The [Co(bpy)(3)](3+) complex cation exhibits C (2) symmetry with the twofold axis through the central Co atom and bis­ecting one bpy ligand...

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Detalles Bibliográficos
Autores principales: Liu, Wen, Xu, Wei, Lin, Jian-Li, Xie, Hong-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959986/
https://www.ncbi.nlm.nih.gov/pubmed/21581186
http://dx.doi.org/10.1107/S1600536808038154
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author Liu, Wen
Xu, Wei
Lin, Jian-Li
Xie, Hong-Zhen
author_facet Liu, Wen
Xu, Wei
Lin, Jian-Li
Xie, Hong-Zhen
author_sort Liu, Wen
collection PubMed
description The title compound, [Co(C(10)H(8)N(2))(3)]Cl(3)·4H(2)O, contains discrete [Co(bpy)(3)](3+) cations (bpy is 2,2′-bipyridine), Cl(−) anions and water mol­ecules. The [Co(bpy)(3)](3+) complex cation exhibits C (2) symmetry with the twofold axis through the central Co atom and bis­ecting one bpy ligand and one of the Cl(−) anions. The four solvent water mol­ecules and the remaining two Cl(−) anions lie on a mirror plane. Hydrogen-bond inter­actions define a two-dimensional layer structure parallel to (100), which consists of seven-membered [Cl(2)(H(2)O)(5)], eight-membered [Cl(4)(H(2)O)(4)] and ten-membered [Cl(2)(H(2)O)(8)] rings.
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spelling pubmed-29599862010-12-30 Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate Liu, Wen Xu, Wei Lin, Jian-Li Xie, Hong-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(10)H(8)N(2))(3)]Cl(3)·4H(2)O, contains discrete [Co(bpy)(3)](3+) cations (bpy is 2,2′-bipyridine), Cl(−) anions and water mol­ecules. The [Co(bpy)(3)](3+) complex cation exhibits C (2) symmetry with the twofold axis through the central Co atom and bis­ecting one bpy ligand and one of the Cl(−) anions. The four solvent water mol­ecules and the remaining two Cl(−) anions lie on a mirror plane. Hydrogen-bond inter­actions define a two-dimensional layer structure parallel to (100), which consists of seven-membered [Cl(2)(H(2)O)(5)], eight-membered [Cl(4)(H(2)O)(4)] and ten-membered [Cl(2)(H(2)O)(8)] rings. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959986/ /pubmed/21581186 http://dx.doi.org/10.1107/S1600536808038154 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Wen
Xu, Wei
Lin, Jian-Li
Xie, Hong-Zhen
Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate
title Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate
title_full Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate
title_fullStr Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate
title_full_unstemmed Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate
title_short Tris(2,2′-bipyridine-κ(2) N:N′)cobalt(III) trichloride tetra­hydrate
title_sort tris(2,2′-bipyridine-κ(2) n:n′)cobalt(iii) trichloride tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959986/
https://www.ncbi.nlm.nih.gov/pubmed/21581186
http://dx.doi.org/10.1107/S1600536808038154
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AT xiehongzhen tris22bipyridinek2nncobaltiiitrichloridetetrahydrate

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