Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate

In the crystal structure of the title compound, [Co(C(12)H(8)N(2))(3)](BF(4))(2)·CH(3)CN, the mol­ecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π–π [centroid–centroid = 3.542 (4) Å] and two C—H⋯π inter­actions [2.573 (4) Å] resulting in a...

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Detalles Bibliográficos
Autores principales: Harding, David J., Harding, Phimphaka, Adams, Harry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959989/
https://www.ncbi.nlm.nih.gov/pubmed/21581152
http://dx.doi.org/10.1107/S1600536808036611
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author Harding, David J.
Harding, Phimphaka
Adams, Harry
author_facet Harding, David J.
Harding, Phimphaka
Adams, Harry
author_sort Harding, David J.
collection PubMed
description In the crystal structure of the title compound, [Co(C(12)H(8)N(2))(3)](BF(4))(2)·CH(3)CN, the mol­ecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π–π [centroid–centroid = 3.542 (4) Å] and two C—H⋯π inter­actions [2.573 (4) Å] resulting in a P4AE (Parallel Fourfold Aryl Embrace) motif. The anions are found in aryl boxes formed from the phenanthroline ligands.
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spelling pubmed-29599892010-12-30 Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate Harding, David J. Harding, Phimphaka Adams, Harry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Co(C(12)H(8)N(2))(3)](BF(4))(2)·CH(3)CN, the mol­ecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π–π [centroid–centroid = 3.542 (4) Å] and two C—H⋯π inter­actions [2.573 (4) Å] resulting in a P4AE (Parallel Fourfold Aryl Embrace) motif. The anions are found in aryl boxes formed from the phenanthroline ligands. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2959989/ /pubmed/21581152 http://dx.doi.org/10.1107/S1600536808036611 Text en © Harding et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harding, David J.
Harding, Phimphaka
Adams, Harry
Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate
title Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate
title_full Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate
title_fullStr Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate
title_full_unstemmed Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate
title_short Tris(phenanthroline-κ(2) N,N′)cobalt(II) tetra­fluoridoborate acetonitrile solvate
title_sort tris(phenanthroline-κ(2) n,n′)cobalt(ii) tetra­fluoridoborate acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959989/
https://www.ncbi.nlm.nih.gov/pubmed/21581152
http://dx.doi.org/10.1107/S1600536808036611
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