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catena-Poly[[di-μ-chlorido-bis­{[6-methoxy-2-(4-methyl­phenyl­iminio­methyl)phenolato-κ(2) O,O′]cadmium(II)}]-di-μ(2)-thio­cyanato-κ(2) N:S;κ(2) S:N]

The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methyl­phenyl­imino)meth­yl]-6-methoxy­phenol (HL) ligand, one thio­cyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via...

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Detalles Bibliográficos
Autores principales: Li, Hua-Qiong, Xian, Hui-Duo, Liu, Jian-Feng, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959993/
https://www.ncbi.nlm.nih.gov/pubmed/21581192
http://dx.doi.org/10.1107/S1600536808038099
Descripción
Sumario:The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methyl­phenyl­imino)meth­yl]-6-methoxy­phenol (HL) ligand, one thio­cyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thio­cyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The Cd(II) coordination environment contains two Cl atoms, one thio­cyanate (SCN) S atom, one isothio­cyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation.