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catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2) O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2) N:S;κ(2) S:N]
The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959993/ https://www.ncbi.nlm.nih.gov/pubmed/21581192 http://dx.doi.org/10.1107/S1600536808038099 |
Sumario: | The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thiocyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The Cd(II) coordination environment contains two Cl atoms, one thiocyanate (SCN) S atom, one isothiocyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation. |
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