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catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2) O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2) N:S;κ(2) S:N]
The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959993/ https://www.ncbi.nlm.nih.gov/pubmed/21581192 http://dx.doi.org/10.1107/S1600536808038099 |
| _version_ | 1782188632904302592 |
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| author | Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang |
| author_facet | Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang |
| author_sort | Li, Hua-Qiong |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thiocyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The Cd(II) coordination environment contains two Cl atoms, one thiocyanate (SCN) S atom, one isothiocyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation. |
| format | Text |
| id | pubmed-2959993 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29599932010-12-30 catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2) O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2) N:S;κ(2) S:N] Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(2)Cl(2)(NCS)(2)(C(15)H(15)NO(2))(2)](n), contains the Schiff base 2-[(4-methylphenylimino)methyl]-6-methoxyphenol (HL) ligand, one thiocyanate and one chloride ligand coordinated to a cadmium centre. The cadmium centers are linked to each other via two thiocyanate and two chloride bridges alternately, resulting in centrosymmetric zigzag chains running parallel to the a axis. The Cd(II) coordination environment contains two Cl atoms, one thiocyanate (SCN) S atom, one isothiocyanate (NCS) N atom and two O atoms from the HL ligand. The Schiff base ligand is in the trans conformation. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2959993/ /pubmed/21581192 http://dx.doi.org/10.1107/S1600536808038099 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Hua-Qiong Xian, Hui-Duo Liu, Jian-Feng Zhao, Guo-Liang catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2) O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2) N:S;κ(2) S:N] |
| title |
catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N] |
| title_full |
catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N] |
| title_fullStr |
catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N] |
| title_full_unstemmed |
catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N] |
| title_short |
catena-Poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2)
O,O′]cadmium(II)}]-di-μ(2)-thiocyanato-κ(2)
N:S;κ(2)
S:N] |
| title_sort | catena-poly[[di-μ-chlorido-bis{[6-methoxy-2-(4-methylphenyliminiomethyl)phenolato-κ(2)
o,o′]cadmium(ii)}]-di-μ(2)-thiocyanato-κ(2)
n:s;κ(2)
s:n] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959993/ https://www.ncbi.nlm.nih.gov/pubmed/21581192 http://dx.doi.org/10.1107/S1600536808038099 |
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