2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane

In the title compound,, [Fe(C(5)H(5))(C(17)H(20)BO(2))], the two near parallel cyclo­penta­dienyl rings of the ferrocene group are eclipsed. The benzene ring is tilted with respect to the attached cyclo­penta­diene ring by 17.0 (1)° and by 24.2 (1)° with respect to the dioxaborolane ring. The mol­ec...

Descripción completa

Detalles Bibliográficos
Autores principales: Boyd, Peter D. W., Paauwe, J. D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959994/
https://www.ncbi.nlm.nih.gov/pubmed/21581115
http://dx.doi.org/10.1107/S1600536808035228
_version_ 1782188633131843584
author Boyd, Peter D. W.
Paauwe, J. D.
author_facet Boyd, Peter D. W.
Paauwe, J. D.
author_sort Boyd, Peter D. W.
collection PubMed
description In the title compound,, [Fe(C(5)H(5))(C(17)H(20)BO(2))], the two near parallel cyclo­penta­dienyl rings of the ferrocene group are eclipsed. The benzene ring is tilted with respect to the attached cyclo­penta­diene ring by 17.0 (1)° and by 24.2 (1)° with respect to the dioxaborolane ring. The mol­ecules assemble in the crystal via C—H⋯π inter­actions between the cyclo­penta­dienyl H atoms and the benzene and cyclo­penta­dienyl rings of neighbouring mol­ecules.
format Text
id pubmed-2959994
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29599942010-12-30 2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane Boyd, Peter D. W. Paauwe, J. D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound,, [Fe(C(5)H(5))(C(17)H(20)BO(2))], the two near parallel cyclo­penta­dienyl rings of the ferrocene group are eclipsed. The benzene ring is tilted with respect to the attached cyclo­penta­diene ring by 17.0 (1)° and by 24.2 (1)° with respect to the dioxaborolane ring. The mol­ecules assemble in the crystal via C—H⋯π inter­actions between the cyclo­penta­dienyl H atoms and the benzene and cyclo­penta­dienyl rings of neighbouring mol­ecules. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2959994/ /pubmed/21581115 http://dx.doi.org/10.1107/S1600536808035228 Text en © Boyd and Paauwe 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boyd, Peter D. W.
Paauwe, J. D.
2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane
title 2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane
title_full 2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane
title_fullStr 2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane
title_full_unstemmed 2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane
title_short 2-(4-Ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane
title_sort 2-(4-ferrocenylphen­yl)-4,4,5,5-tetra­methyl-1,3,2-dioxaborolane
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959994/
https://www.ncbi.nlm.nih.gov/pubmed/21581115
http://dx.doi.org/10.1107/S1600536808035228
work_keys_str_mv AT boydpeterdw 24ferrocenylphenyl4455tetramethyl132dioxaborolane
AT paauwejd 24ferrocenylphenyl4455tetramethyl132dioxaborolane

Ejemplares similares