Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate

The Co(II) ion in the title complex, [Co(2)(C(4)H(5)O(2))(4)(C(15)H(13)N(5))(2)]·2H(2)O, has a distorted square-planar coordination formed by the bridging bidentate N,N′-di-4-pyridylpyrid­ine-2,6-diamine (dapmp) ligands and two monodentate carboxyl­ate groups from methacrylates. Two dapmp ligands br...

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Detalles Bibliográficos
Autores principales: Wang, Liang-Gui, Peng, Ai-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959996/
https://www.ncbi.nlm.nih.gov/pubmed/21581181
http://dx.doi.org/10.1107/S1600536808037847
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author Wang, Liang-Gui
Peng, Ai-Hua
author_facet Wang, Liang-Gui
Peng, Ai-Hua
author_sort Wang, Liang-Gui
collection PubMed
description The Co(II) ion in the title complex, [Co(2)(C(4)H(5)O(2))(4)(C(15)H(13)N(5))(2)]·2H(2)O, has a distorted square-planar coordination formed by the bridging bidentate N,N′-di-4-pyridylpyrid­ine-2,6-diamine (dapmp) ligands and two monodentate carboxyl­ate groups from methacrylates. Two dapmp ligands bridge two Co atoms, forming a dinuclear complex arranged around an inversion centre. N—H⋯O and O—H⋯O hydrogen bonds involving the solvent water mol­ecule result in the formation of a three-dimensional network. The aliphatic moiety of one of the methacrylate groups is disordered over two positions with fixed occupancies of 0.67 and 0.33.
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spelling pubmed-29599962010-12-30 Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate Wang, Liang-Gui Peng, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) ion in the title complex, [Co(2)(C(4)H(5)O(2))(4)(C(15)H(13)N(5))(2)]·2H(2)O, has a distorted square-planar coordination formed by the bridging bidentate N,N′-di-4-pyridylpyrid­ine-2,6-diamine (dapmp) ligands and two monodentate carboxyl­ate groups from methacrylates. Two dapmp ligands bridge two Co atoms, forming a dinuclear complex arranged around an inversion centre. N—H⋯O and O—H⋯O hydrogen bonds involving the solvent water mol­ecule result in the formation of a three-dimensional network. The aliphatic moiety of one of the methacrylate groups is disordered over two positions with fixed occupancies of 0.67 and 0.33. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959996/ /pubmed/21581181 http://dx.doi.org/10.1107/S1600536808037847 Text en © Wang & Peng 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Liang-Gui
Peng, Ai-Hua
Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate
title Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate
title_full Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate
title_fullStr Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate
title_full_unstemmed Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate
title_short Bis(μ-N,N′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(II)] dihydrate
title_sort bis(μ-n,n′-di-4-pyridylpyridine-2,6-diamine)bis[dimethacrylatocobalt(ii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959996/
https://www.ncbi.nlm.nih.gov/pubmed/21581181
http://dx.doi.org/10.1107/S1600536808037847
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AT pengaihua bismnndi4pyridylpyridine26diaminebisdimethacrylatocobaltiidihydrate

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