Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II)

In the title compound, (C(16)H(36)N)(2)[Pd(C(4)N(2)S(2))(2)], the Pd(II) center adopts a distorted square-planar geometry due to the four-membered chelate rings formed by coordination of the 2,2-dicyano­ethyl­ene-1,1-dithiol­ate (i-mnt) ligands [bite angle 75.0159 (17)°]. The bond distances in the c...

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Detalles Bibliográficos
Autores principales: Kanganga, Nyasha, Mann, Kent R., Janzen, Daron E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959997/
https://www.ncbi.nlm.nih.gov/pubmed/21581171
http://dx.doi.org/10.1107/S1600536808037616
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author Kanganga, Nyasha
Mann, Kent R.
Janzen, Daron E.
author_facet Kanganga, Nyasha
Mann, Kent R.
Janzen, Daron E.
author_sort Kanganga, Nyasha
collection PubMed
description In the title compound, (C(16)H(36)N)(2)[Pd(C(4)N(2)S(2))(2)], the Pd(II) center adopts a distorted square-planar geometry due to the four-membered chelate rings formed by coordination of the 2,2-dicyano­ethyl­ene-1,1-dithiol­ate (i-mnt) ligands [bite angle 75.0159 (17)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.
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spelling pubmed-29599972010-12-30 Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II) Kanganga, Nyasha Mann, Kent R. Janzen, Daron E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(16)H(36)N)(2)[Pd(C(4)N(2)S(2))(2)], the Pd(II) center adopts a distorted square-planar geometry due to the four-membered chelate rings formed by coordination of the 2,2-dicyano­ethyl­ene-1,1-dithiol­ate (i-mnt) ligands [bite angle 75.0159 (17)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2959997/ /pubmed/21581171 http://dx.doi.org/10.1107/S1600536808037616 Text en © Kanganga et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kanganga, Nyasha
Mann, Kent R.
Janzen, Daron E.
Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II)
title Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II)
title_full Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II)
title_fullStr Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II)
title_full_unstemmed Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II)
title_short Tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(II)
title_sort tetra-n-butyl­ammonium bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959997/
https://www.ncbi.nlm.nih.gov/pubmed/21581171
http://dx.doi.org/10.1107/S1600536808037616
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AT mannkentr tetranbutylammoniumbis22dicyanoethylene11dithiolatopalladiumii
AT janzendarone tetranbutylammoniumbis22dicyanoethylene11dithiolatopalladiumii

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