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Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)]
In the title compound, [Cd(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n), the coordination polyhedron around each Cd(II) ion is a distorted CdNO(5) octahedron. The water O atom has site symmetry 2 and the complete 1,1′-(butane-1,4-diyl)diimidazole (L) ligand is generated by inversion. The naphth...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960000/ https://www.ncbi.nlm.nih.gov/pubmed/21581169 http://dx.doi.org/10.1107/S1600536808037525 |
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author | Xu, Qun Zhang, Wen-Zhi Chen, Zhi-Qiang |
author_facet | Xu, Qun Zhang, Wen-Zhi Chen, Zhi-Qiang |
author_sort | Xu, Qun |
collection | PubMed |
description | In the title compound, [Cd(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n), the coordination polyhedron around each Cd(II) ion is a distorted CdNO(5) octahedron. The water O atom has site symmetry 2 and the complete 1,1′-(butane-1,4-diyl)diimidazole (L) ligand is generated by inversion. The naphthalene-1,4-dicarboxylate and L ligands bridge the metal centres, forming a three-dimensional framework, which is consolidated by O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2960000 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29600002010-12-30 Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)] Xu, Qun Zhang, Wen-Zhi Chen, Zhi-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)(C(12)H(6)O(4))(2)(C(10)H(14)N(4))(H(2)O)](n), the coordination polyhedron around each Cd(II) ion is a distorted CdNO(5) octahedron. The water O atom has site symmetry 2 and the complete 1,1′-(butane-1,4-diyl)diimidazole (L) ligand is generated by inversion. The naphthalene-1,4-dicarboxylate and L ligands bridge the metal centres, forming a three-dimensional framework, which is consolidated by O—H⋯O hydrogen bonds. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2960000/ /pubmed/21581169 http://dx.doi.org/10.1107/S1600536808037525 Text en © Xu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Qun Zhang, Wen-Zhi Chen, Zhi-Qiang Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)] |
title | Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)] |
title_full | Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)] |
title_fullStr | Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)] |
title_full_unstemmed | Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)] |
title_short | Poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(II)] |
title_sort | poly[μ-aqua-[μ-1,1′-(butane-1,4-diyl)diimidazole]bis(μ(4)-naphthalene-1,4-dicarboxylato)dicadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960000/ https://www.ncbi.nlm.nih.gov/pubmed/21581169 http://dx.doi.org/10.1107/S1600536808037525 |
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