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catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butylisophthalato]
In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butylisophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordinated by two N atoms from bipy and two O atom...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960003/ https://www.ncbi.nlm.nih.gov/pubmed/21581122 http://dx.doi.org/10.1107/S1600536808035484 |
Sumario: | In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butylisophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordinated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6) |
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