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catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]

In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl­isophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordin­ated by two N atoms from bipy and two O atom...

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Detalles Bibliográficos
Autores principales: Li, Xiao-Ling, Huang, Miao-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960003/
https://www.ncbi.nlm.nih.gov/pubmed/21581122
http://dx.doi.org/10.1107/S1600536808035484
Descripción
Sumario:In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl­isophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordin­ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6)