catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]

In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl­isophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordin­ated by two N atoms from bipy and two O atom...

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Detalles Bibliográficos
Autores principales: Li, Xiao-Ling, Huang, Miao-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960003/
https://www.ncbi.nlm.nih.gov/pubmed/21581122
http://dx.doi.org/10.1107/S1600536808035484
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author Li, Xiao-Ling
Huang, Miao-Ling
author_facet Li, Xiao-Ling
Huang, Miao-Ling
author_sort Li, Xiao-Ling
collection PubMed
description In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl­isophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordin­ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6)
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spelling pubmed-29600032010-12-30 catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato] Li, Xiao-Ling Huang, Miao-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title polymeric compound, [Cu(C(12)H(12)O(4))(C(10)H(8)N(2))](n), the asymmetric unit consists of one Cu(II) ion, one 5-tert-butyl­isophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordin­ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6) International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960003/ /pubmed/21581122 http://dx.doi.org/10.1107/S1600536808035484 Text en © Li and Huang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xiao-Ling
Huang, Miao-Ling
catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]
title catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]
title_full catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]
title_fullStr catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]
title_full_unstemmed catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]
title_short catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]
title_sort catena-poly[[(2,2′-bipyridine)copper(ii)]-μ-5-tert-butyl­isophthalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960003/
https://www.ncbi.nlm.nih.gov/pubmed/21581122
http://dx.doi.org/10.1107/S1600536808035484
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