Cargando…
N,N′-Bis(4-chlorobenzylidene)-2,2-dimethylpropane-1,3-diamine
The title compound, C(19)H(20)Cl(2)N(2), is a potential bidentate Schiff base ligand. Intramolecular C—H⋯N hydrogen bonds form five-membered rings, generating S(5) ring motifs. Each imino functional group is coplanar with its adjacent benzene ring; the two benzene rings form a dihedral angle of 51....
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960008/ https://www.ncbi.nlm.nih.gov/pubmed/21581254 http://dx.doi.org/10.1107/S1600536808035307 |
Sumario: | The title compound, C(19)H(20)Cl(2)N(2), is a potential bidentate Schiff base ligand. Intramolecular C—H⋯N hydrogen bonds form five-membered rings, generating S(5) ring motifs. Each imino functional group is coplanar with its adjacent benzene ring; the two benzene rings form a dihedral angle of 51.30 (4)°. An interesting feature of the crystal structure is weak intermolecular Cl⋯Cl [3.4752 (4) Å] and Cl⋯N [3.2927 (9) Å] interactions. Intermolecular Cl⋯N interactions link molecules into dimers with R(2)(2)(22) ring motifs. The crystal structure is further stabilized by weak π–π [centroid–centroid distances = 3.6970 (6)–3.8560 (6) Å] interactions. |
---|