N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine

The title compound, C(19)H(20)Cl(2)N(2), is a potential bidentate Schiff base ligand. Intra­molecular C—H⋯N hydrogen bonds form five-membered rings, generating S(5) ring motifs. Each imino functional group is coplanar with its adjacent benzene ring; the two benzene rings form a dihedral angle of 51....

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kargar, Hadi, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960008/
https://www.ncbi.nlm.nih.gov/pubmed/21581254
http://dx.doi.org/10.1107/S1600536808035307
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author Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
author_facet Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(19)H(20)Cl(2)N(2), is a potential bidentate Schiff base ligand. Intra­molecular C—H⋯N hydrogen bonds form five-membered rings, generating S(5) ring motifs. Each imino functional group is coplanar with its adjacent benzene ring; the two benzene rings form a dihedral angle of 51.30 (4)°. An inter­esting feature of the crystal structure is weak inter­molecular Cl⋯Cl [3.4752 (4) Å] and Cl⋯N [3.2927 (9) Å] inter­actions. Inter­molecular Cl⋯N inter­actions link mol­ecules into dimers with R(2)(2)(22) ring motifs. The crystal structure is further stabilized by weak π–π [centroid–centroid distances = 3.6970 (6)–3.8560 (6) Å] inter­actions.
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spelling pubmed-29600082010-12-30 N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine Fun, Hoong-Kun Kargar, Hadi Kia, Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(20)Cl(2)N(2), is a potential bidentate Schiff base ligand. Intra­molecular C—H⋯N hydrogen bonds form five-membered rings, generating S(5) ring motifs. Each imino functional group is coplanar with its adjacent benzene ring; the two benzene rings form a dihedral angle of 51.30 (4)°. An inter­esting feature of the crystal structure is weak inter­molecular Cl⋯Cl [3.4752 (4) Å] and Cl⋯N [3.2927 (9) Å] inter­actions. Inter­molecular Cl⋯N inter­actions link mol­ecules into dimers with R(2)(2)(22) ring motifs. The crystal structure is further stabilized by weak π–π [centroid–centroid distances = 3.6970 (6)–3.8560 (6) Å] inter­actions. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960008/ /pubmed/21581254 http://dx.doi.org/10.1107/S1600536808035307 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_full N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_fullStr N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_full_unstemmed N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_short N,N′-Bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_sort n,n′-bis(4-chloro­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960008/
https://www.ncbi.nlm.nih.gov/pubmed/21581254
http://dx.doi.org/10.1107/S1600536808035307
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AT kargarhadi nnbis4chlorobenzylidene22dimethylpropane13diamine
AT kiareza nnbis4chlorobenzylidene22dimethylpropane13diamine

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