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catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methylisophthalato]
In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn—N = 2.273 (3) and 2.305 (2) Å] from a 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.112 (2)–2.343 (3) Å] from three 5-methylisophthalate (mip) ligands in a distorted octahedral geo...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960010/ https://www.ncbi.nlm.nih.gov/pubmed/21581139 http://dx.doi.org/10.1107/S1600536808036362 |
| Sumario: | In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn—N = 2.273 (3) and 2.305 (2) Å] from a 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.112 (2)–2.343 (3) Å] from three 5-methylisophthalate (mip) ligands in a distorted octahedral geometry. Each mip dianion acts as a tetradentate ligand connecting three Mn ions. The crystal packing exhibits π–π interactions [3.599 (2)–3.755 (2) Å] between the centroids of the six-membered rings of neighbouring 1,10-phenanthroline ligands. |
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