catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato]

In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn—N = 2.273 (3) and 2.305 (2) Å] from a 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.112 (2)–2.343 (3) Å] from three 5-methyl­isophthalate (mip) ligands in a distorted octa­hedral geo...

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Detalles Bibliográficos
Autores principales: Yu, Zhao-Lian, Hu, Jiang-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960010/
https://www.ncbi.nlm.nih.gov/pubmed/21581139
http://dx.doi.org/10.1107/S1600536808036362
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author Yu, Zhao-Lian
Hu, Jiang-Liang
author_facet Yu, Zhao-Lian
Hu, Jiang-Liang
author_sort Yu, Zhao-Lian
collection PubMed
description In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn—N = 2.273 (3) and 2.305 (2) Å] from a 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.112 (2)–2.343 (3) Å] from three 5-methyl­isophthalate (mip) ligands in a distorted octa­hedral geometry. Each mip dianion acts as a tetra­dentate ligand connecting three Mn ions. The crystal packing exhibits π–π inter­actions [3.599 (2)–3.755 (2) Å] between the centroids of the six-membered rings of neighbouring 1,10-phenanthroline ligands.
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spelling pubmed-29600102010-12-30 catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato] Yu, Zhao-Lian Hu, Jiang-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn—N = 2.273 (3) and 2.305 (2) Å] from a 1,10-phenanthroline ligand and four O atoms [Mn—O = 2.112 (2)–2.343 (3) Å] from three 5-methyl­isophthalate (mip) ligands in a distorted octa­hedral geometry. Each mip dianion acts as a tetra­dentate ligand connecting three Mn ions. The crystal packing exhibits π–π inter­actions [3.599 (2)–3.755 (2) Å] between the centroids of the six-membered rings of neighbouring 1,10-phenanthroline ligands. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960010/ /pubmed/21581139 http://dx.doi.org/10.1107/S1600536808036362 Text en © Yu and Hu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Zhao-Lian
Hu, Jiang-Liang
catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato]
title catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato]
title_full catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato]
title_fullStr catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato]
title_short catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl­isophthalato]
title_sort catena-poly[[(1,10-phenanthroline)manganese(ii)]-μ(3)-5-methyl­isophthalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960010/
https://www.ncbi.nlm.nih.gov/pubmed/21581139
http://dx.doi.org/10.1107/S1600536808036362
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