N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide

The title mol­ecule, C(22)H(8)F(14)N(2)O(4), lies across a crystallographic inversion center with the naphthalene diimide core essentially planar (mean deviation from plane is 0.0583 Å). The CF(2) groups in the perfluorobutyl chains are in an energetically favorable all trans conformation. In the cr...

Descripción completa

Detalles Bibliográficos
Autores principales: Shukla, Deepak, Rajeswaran, Manju, Ahearn, Wendy G., Meyer, Dianne M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960015/
https://www.ncbi.nlm.nih.gov/pubmed/21581302
http://dx.doi.org/10.1107/S1600536808036738
_version_ 1782188638225825792
author Shukla, Deepak
Rajeswaran, Manju
Ahearn, Wendy G.
Meyer, Dianne M.
author_facet Shukla, Deepak
Rajeswaran, Manju
Ahearn, Wendy G.
Meyer, Dianne M.
author_sort Shukla, Deepak
collection PubMed
description The title mol­ecule, C(22)H(8)F(14)N(2)O(4), lies across a crystallographic inversion center with the naphthalene diimide core essentially planar (mean deviation from plane is 0.0583 Å). The CF(2) groups in the perfluorobutyl chains are in an energetically favorable all trans conformation. In the crystal structure, mol­ecules are packed in slightly displaced layers so that the side chains overlap the aromatic naphthalene diimide rings, thus minimizing any possible π–π overlap.
format Text
id pubmed-2960015
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29600152010-12-30 N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide Shukla, Deepak Rajeswaran, Manju Ahearn, Wendy G. Meyer, Dianne M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(22)H(8)F(14)N(2)O(4), lies across a crystallographic inversion center with the naphthalene diimide core essentially planar (mean deviation from plane is 0.0583 Å). The CF(2) groups in the perfluorobutyl chains are in an energetically favorable all trans conformation. In the crystal structure, mol­ecules are packed in slightly displaced layers so that the side chains overlap the aromatic naphthalene diimide rings, thus minimizing any possible π–π overlap. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960015/ /pubmed/21581302 http://dx.doi.org/10.1107/S1600536808036738 Text en © Shukla et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shukla, Deepak
Rajeswaran, Manju
Ahearn, Wendy G.
Meyer, Dianne M.
N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide
title N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide
title_full N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide
title_fullStr N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide
title_full_unstemmed N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide
title_short N,N′-Bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide
title_sort n,n′-bis(2,2,3,3,4,4,4-hepta­fluoro­butyl)naphthalene-1,4:5,8-tetra­carboximide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960015/
https://www.ncbi.nlm.nih.gov/pubmed/21581302
http://dx.doi.org/10.1107/S1600536808036738
work_keys_str_mv AT shukladeepak nnbis2233444heptafluorobutylnaphthalene1458tetracarboximide
AT rajeswaranmanju nnbis2233444heptafluorobutylnaphthalene1458tetracarboximide
AT ahearnwendyg nnbis2233444heptafluorobutylnaphthalene1458tetracarboximide
AT meyerdiannem nnbis2233444heptafluorobutylnaphthalene1458tetracarboximide

Ejemplares similares