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N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine

The title compound, C(13)H(9)N(5)O(6), contains three nitro groups. It is prepared by the reaction of benzaldehyde 2,4-dinitro­phenyl­hydrazone with nitric oxide at ambient temperature. The imine group is nearly coplanar with the (2,4-dinitro­phen­yl)­hydrazine unit. The second benzene ring and the...

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Detalles Bibliográficos
Autor principal: Yuan, Chunlan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960026/
https://www.ncbi.nlm.nih.gov/pubmed/21581275
http://dx.doi.org/10.1107/S1600536808036179
Descripción
Sumario:The title compound, C(13)H(9)N(5)O(6), contains three nitro groups. It is prepared by the reaction of benzaldehyde 2,4-dinitro­phenyl­hydrazone with nitric oxide at ambient temperature. The imine group is nearly coplanar with the (2,4-dinitro­phen­yl)­hydrazine unit. The second benzene ring and the third nitro group are twisted away from this plane, with dihedral angles of 48.5 (3) and 15.2 (3)°, respectively. Weak intra­molecular N—H⋯O inter­actions are observed.