N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine

The title compound, C(13)H(9)N(5)O(6), contains three nitro groups. It is prepared by the reaction of benzaldehyde 2,4-dinitro­phenyl­hydrazone with nitric oxide at ambient temperature. The imine group is nearly coplanar with the (2,4-dinitro­phen­yl)­hydrazine unit. The second benzene ring and the...

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Detalles Bibliográficos
Autor principal: Yuan, Chunlan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960026/
https://www.ncbi.nlm.nih.gov/pubmed/21581275
http://dx.doi.org/10.1107/S1600536808036179
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author Yuan, Chunlan
author_facet Yuan, Chunlan
author_sort Yuan, Chunlan
collection PubMed
description The title compound, C(13)H(9)N(5)O(6), contains three nitro groups. It is prepared by the reaction of benzaldehyde 2,4-dinitro­phenyl­hydrazone with nitric oxide at ambient temperature. The imine group is nearly coplanar with the (2,4-dinitro­phen­yl)­hydrazine unit. The second benzene ring and the third nitro group are twisted away from this plane, with dihedral angles of 48.5 (3) and 15.2 (3)°, respectively. Weak intra­molecular N—H⋯O inter­actions are observed.
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spelling pubmed-29600262010-12-30 N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine Yuan, Chunlan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(9)N(5)O(6), contains three nitro groups. It is prepared by the reaction of benzaldehyde 2,4-dinitro­phenyl­hydrazone with nitric oxide at ambient temperature. The imine group is nearly coplanar with the (2,4-dinitro­phen­yl)­hydrazine unit. The second benzene ring and the third nitro group are twisted away from this plane, with dihedral angles of 48.5 (3) and 15.2 (3)°, respectively. Weak intra­molecular N—H⋯O inter­actions are observed. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960026/ /pubmed/21581275 http://dx.doi.org/10.1107/S1600536808036179 Text en © Chunlan Yuan 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yuan, Chunlan
N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine
title N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine
title_full N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine
title_fullStr N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine
title_full_unstemmed N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine
title_short N-(2,4-Dinitro­phen­yl)-N′-[nitro­(phenyl)­methyl­ene]hydrazine
title_sort n-(2,4-dinitro­phen­yl)-n′-[nitro­(phenyl)­methyl­ene]hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960026/
https://www.ncbi.nlm.nih.gov/pubmed/21581275
http://dx.doi.org/10.1107/S1600536808036179
work_keys_str_mv AT yuanchunlan n24dinitrophenylnnitrophenylmethylenehydrazine

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