Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)

In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy­imino­methyl-6-methoxy­phenolate ligands. Intra­molecular O—H⋯O hydrogen bonds are formed and the...

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Detalles Bibliográficos
Autores principales: Zhang, Shu Hua, Ge, Cheng Min, Feng, Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960033/
https://www.ncbi.nlm.nih.gov/pubmed/21581217
http://dx.doi.org/10.1107/S1600536808039512
Descripción
Sumario:In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy­imino­methyl-6-methoxy­phenolate ligands. Intra­molecular O—H⋯O hydrogen bonds are formed and the complexes form stacks along the b axis, with an inter­planar separation of 3.332 (1) Å between complexes. Pairs of C—H⋯O contacts are formed between complexes in neighbouring stacks.

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