Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)

In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy­imino­methyl-6-methoxy­phenolate ligands. Intra­molecular O—H⋯O hydrogen bonds are formed and the...

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Detalles Bibliográficos
Autores principales: Zhang, Shu Hua, Ge, Cheng Min, Feng, Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960033/
https://www.ncbi.nlm.nih.gov/pubmed/21581217
http://dx.doi.org/10.1107/S1600536808039512
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author Zhang, Shu Hua
Ge, Cheng Min
Feng, Chao
author_facet Zhang, Shu Hua
Ge, Cheng Min
Feng, Chao
author_sort Zhang, Shu Hua
collection PubMed
description In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy­imino­methyl-6-methoxy­phenolate ligands. Intra­molecular O—H⋯O hydrogen bonds are formed and the complexes form stacks along the b axis, with an inter­planar separation of 3.332 (1) Å between complexes. Pairs of C—H⋯O contacts are formed between complexes in neighbouring stacks.
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spelling pubmed-29600332010-12-30 Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II) Zhang, Shu Hua Ge, Cheng Min Feng, Chao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy­imino­methyl-6-methoxy­phenolate ligands. Intra­molecular O—H⋯O hydrogen bonds are formed and the complexes form stacks along the b axis, with an inter­planar separation of 3.332 (1) Å between complexes. Pairs of C—H⋯O contacts are formed between complexes in neighbouring stacks. International Union of Crystallography 2008-11-29 /pmc/articles/PMC2960033/ /pubmed/21581217 http://dx.doi.org/10.1107/S1600536808039512 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Shu Hua
Ge, Cheng Min
Feng, Chao
Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)
title Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)
title_full Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)
title_fullStr Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)
title_full_unstemmed Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)
title_short Bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) O (1),N)cobalt(II)
title_sort bis(2-hydroxy­imino­methyl-6-methoxy­phenolato-κ(2) o (1),n)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960033/
https://www.ncbi.nlm.nih.gov/pubmed/21581217
http://dx.doi.org/10.1107/S1600536808039512
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AT fengchao bis2hydroxyiminomethyl6methoxyphenolatok2o1ncobaltii

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