Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate

In the title centrosymmetric binuclear complex, [Y(2)(C(10)H(6)NO(2))(6)(H(2)O)(4)]·2H(2)O, each Y(III) atom is nine-coordin­ated by nine O atoms from five ligands and two water mol­ecules in a slightly distorted monocapped square-anti­prismatic coordination environment. The Y(III) atoms are separat...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Chao-Yan, Gao, Qian, Cui, Yue, Xie, Ya-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960038/
https://www.ncbi.nlm.nih.gov/pubmed/21581221
http://dx.doi.org/10.1107/S1600536808039421
Descripción
Sumario:In the title centrosymmetric binuclear complex, [Y(2)(C(10)H(6)NO(2))(6)(H(2)O)(4)]·2H(2)O, each Y(III) atom is nine-coordin­ated by nine O atoms from five ligands and two water mol­ecules in a slightly distorted monocapped square-anti­prismatic coordination environment. The Y(III) atoms are separated by a distance of 4.0363 (9) Å. The ligands coordinate in three different modes: chelating, bridging and a mixed chelating bridging mode. In the crystal structure, the binuclear complexes are linked by O—H⋯O and O—H⋯N hydrogen bonds, forming a three-dimensional network.

Ejemplares similares