Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate

In the title centrosymmetric binuclear complex, [Y(2)(C(10)H(6)NO(2))(6)(H(2)O)(4)]·2H(2)O, each Y(III) atom is nine-coordin­ated by nine O atoms from five ligands and two water mol­ecules in a slightly distorted monocapped square-anti­prismatic coordination environment. The Y(III) atoms are separat...

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Detalles Bibliográficos
Autores principales: Zhang, Chao-Yan, Gao, Qian, Cui, Yue, Xie, Ya-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960038/
https://www.ncbi.nlm.nih.gov/pubmed/21581221
http://dx.doi.org/10.1107/S1600536808039421
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author Zhang, Chao-Yan
Gao, Qian
Cui, Yue
Xie, Ya-Bo
author_facet Zhang, Chao-Yan
Gao, Qian
Cui, Yue
Xie, Ya-Bo
author_sort Zhang, Chao-Yan
collection PubMed
description In the title centrosymmetric binuclear complex, [Y(2)(C(10)H(6)NO(2))(6)(H(2)O)(4)]·2H(2)O, each Y(III) atom is nine-coordin­ated by nine O atoms from five ligands and two water mol­ecules in a slightly distorted monocapped square-anti­prismatic coordination environment. The Y(III) atoms are separated by a distance of 4.0363 (9) Å. The ligands coordinate in three different modes: chelating, bridging and a mixed chelating bridging mode. In the crystal structure, the binuclear complexes are linked by O—H⋯O and O—H⋯N hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29600382010-12-30 Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate Zhang, Chao-Yan Gao, Qian Cui, Yue Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric binuclear complex, [Y(2)(C(10)H(6)NO(2))(6)(H(2)O)(4)]·2H(2)O, each Y(III) atom is nine-coordin­ated by nine O atoms from five ligands and two water mol­ecules in a slightly distorted monocapped square-anti­prismatic coordination environment. The Y(III) atoms are separated by a distance of 4.0363 (9) Å. The ligands coordinate in three different modes: chelating, bridging and a mixed chelating bridging mode. In the crystal structure, the binuclear complexes are linked by O—H⋯O and O—H⋯N hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2008-11-29 /pmc/articles/PMC2960038/ /pubmed/21581221 http://dx.doi.org/10.1107/S1600536808039421 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Chao-Yan
Gao, Qian
Cui, Yue
Xie, Ya-Bo
Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate
title Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate
title_full Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate
title_fullStr Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate
title_full_unstemmed Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate
title_short Tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(III) dihydrate
title_sort tetra­aqua­hexa­kis(μ(2)-quinoline-4-carboxyl­ato)diyttrium(iii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960038/
https://www.ncbi.nlm.nih.gov/pubmed/21581221
http://dx.doi.org/10.1107/S1600536808039421
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AT gaoqian tetraaquahexakism2quinoline4carboxylatodiyttriumiiidihydrate
AT cuiyue tetraaquahexakism2quinoline4carboxylatodiyttriumiiidihydrate
AT xieyabo tetraaquahexakism2quinoline4carboxylatodiyttriumiiidihydrate

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