2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene

There are two independent mol­ecules in the asymmetric unit of the title compound, C(20)H(36)S. Crystals are non-merohedrally twinned by twofold rotation about [001]. The bulky octyl groups of each mol­ecule are on the same side of the thio­phene plane and are approximately parallel. S—C distances a...

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Detalles Bibliográficos
Autores principales: Elnagar, Hassan Y., Sabahi, Mahmood, Gatto, Vince J., Fronczek, Frank R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960047/
https://www.ncbi.nlm.nih.gov/pubmed/21581366
http://dx.doi.org/10.1107/S1600536808037434
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author Elnagar, Hassan Y.
Sabahi, Mahmood
Gatto, Vince J.
Fronczek, Frank R.
author_facet Elnagar, Hassan Y.
Sabahi, Mahmood
Gatto, Vince J.
Fronczek, Frank R.
author_sort Elnagar, Hassan Y.
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(20)H(36)S. Crystals are non-merohedrally twinned by twofold rotation about [001]. The bulky octyl groups of each mol­ecule are on the same side of the thio­phene plane and are approximately parallel. S—C distances are in the range 1.729 (4)–1.745 (3) Å, and the C—S—C angles are 92.98 (18) and 93.08 (17)°. The CH(2) groups of the octyl groups are involved in weak C—H⋯S intra­molecular inter­actions.
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spelling pubmed-29600472010-12-30 2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene Elnagar, Hassan Y. Sabahi, Mahmood Gatto, Vince J. Fronczek, Frank R. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(20)H(36)S. Crystals are non-merohedrally twinned by twofold rotation about [001]. The bulky octyl groups of each mol­ecule are on the same side of the thio­phene plane and are approximately parallel. S—C distances are in the range 1.729 (4)–1.745 (3) Å, and the C—S—C angles are 92.98 (18) and 93.08 (17)°. The CH(2) groups of the octyl groups are involved in weak C—H⋯S intra­molecular inter­actions. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2960047/ /pubmed/21581366 http://dx.doi.org/10.1107/S1600536808037434 Text en © Elnagar et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Elnagar, Hassan Y.
Sabahi, Mahmood
Gatto, Vince J.
Fronczek, Frank R.
2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene
title 2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene
title_full 2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene
title_fullStr 2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene
title_full_unstemmed 2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene
title_short 2,5-Bis(1,1,3,3-tetra­methyl­butyl)thio­phene
title_sort 2,5-bis(1,1,3,3-tetra­methyl­butyl)thio­phene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960047/
https://www.ncbi.nlm.nih.gov/pubmed/21581366
http://dx.doi.org/10.1107/S1600536808037434
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AT fronczekfrankr 25bis1133tetramethylbutylthiophene

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