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2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate

In the title mol­ecule, C(17)H(15)NO(5)S, the dihedral angle between the essentially planar atoms of the tosyl moiety (the S atom and the seven tolyl C atoms) and the phthalimide moiety is 6.089 (3)°. The mol­ecule is folded about the ethyl­ene bridge, adopting a staggered conformation such that the...

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Detalles Bibliográficos
Autores principales: Bartholomä, Mark Daniel, Ouellette, Wayne, Zubieta, Jon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960049/
https://www.ncbi.nlm.nih.gov/pubmed/21581365
http://dx.doi.org/10.1107/S1600536808037951
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author Bartholomä, Mark Daniel
Ouellette, Wayne
Zubieta, Jon
author_facet Bartholomä, Mark Daniel
Ouellette, Wayne
Zubieta, Jon
author_sort Bartholomä, Mark Daniel
collection PubMed
description In the title mol­ecule, C(17)H(15)NO(5)S, the dihedral angle between the essentially planar atoms of the tosyl moiety (the S atom and the seven tolyl C atoms) and the phthalimide moiety is 6.089 (3)°. The mol­ecule is folded about the ethyl­ene bridge, adopting a staggered conformation such that the benzene ring of the tosyl group and the five-membered ring of the phthalimide moiety have a face-to-face orientation with a centroid-to-centroid separation of 3.7454 (12) Å. The crystal structure is stabilized by weak inter­molecular π–π inter­actions between symmetry-related five-membered rings of the phthalimide groups, with a centroid-to-centroid distance of 3.3867 (11) Å. The compound is used for the attachment of a suitable chelate functionality for radiolabeling purposes.
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spelling pubmed-29600492010-12-30 2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate Bartholomä, Mark Daniel Ouellette, Wayne Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(17)H(15)NO(5)S, the dihedral angle between the essentially planar atoms of the tosyl moiety (the S atom and the seven tolyl C atoms) and the phthalimide moiety is 6.089 (3)°. The mol­ecule is folded about the ethyl­ene bridge, adopting a staggered conformation such that the benzene ring of the tosyl group and the five-membered ring of the phthalimide moiety have a face-to-face orientation with a centroid-to-centroid separation of 3.7454 (12) Å. The crystal structure is stabilized by weak inter­molecular π–π inter­actions between symmetry-related five-membered rings of the phthalimide groups, with a centroid-to-centroid distance of 3.3867 (11) Å. The compound is used for the attachment of a suitable chelate functionality for radiolabeling purposes. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2960049/ /pubmed/21581365 http://dx.doi.org/10.1107/S1600536808037951 Text en © Bartholomä et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bartholomä, Mark Daniel
Ouellette, Wayne
Zubieta, Jon
2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate
title 2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate
title_full 2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate
title_fullStr 2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate
title_full_unstemmed 2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate
title_short 2-(1,3-Dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate
title_sort 2-(1,3-dioxoisoindolin-2-yl)ethyl 4-methyl­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960049/
https://www.ncbi.nlm.nih.gov/pubmed/21581365
http://dx.doi.org/10.1107/S1600536808037951
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