Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate

The title complex, [Re(C(7)H(2)Br(3)O(2))(CO)(3)(H(2)O)]·CH(3)OH, crystallized as a neutral Re(I) compound and one methanol solvent mol­ecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromo­tropolanate ligand and a water mol­ecule complete the distorted octahedral coordination around the central metal. Inter­molecular Br⋯O [3.226 (5) Å] and Br⋯Br [3.590 (2) Å] contacts are observed between adjacent mol­ecules. These contacts, together with an array of O—H⋯O, O—H⋯Br and C—H⋯O hydrogen bonds, complete a three-dimensional polymeric network formed between the methanol solvent and the complex.