Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate

The title complex, [Re(C(7)H(2)Br(3)O(2))(CO)(3)(H(2)O)]·CH(3)OH, crystallized as a neutral Re(I) compound and one methanol solvent mol­ecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromo­tropolanate ligand and a water mol­ecule com...

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Detalles Bibliográficos
Autores principales: Schutte, Marietjie, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960052/
https://www.ncbi.nlm.nih.gov/pubmed/21581205
http://dx.doi.org/10.1107/S1600536808038737
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author Schutte, Marietjie
Visser, Hendrik G.
Roodt, Andreas
author_facet Schutte, Marietjie
Visser, Hendrik G.
Roodt, Andreas
author_sort Schutte, Marietjie
collection PubMed
description The title complex, [Re(C(7)H(2)Br(3)O(2))(CO)(3)(H(2)O)]·CH(3)OH, crystallized as a neutral Re(I) compound and one methanol solvent mol­ecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromo­tropolanate ligand and a water mol­ecule complete the distorted octahedral coordination around the central metal. Inter­molecular Br⋯O [3.226 (5) Å] and Br⋯Br [3.590 (2) Å] contacts are observed between adjacent mol­ecules. These contacts, together with an array of O—H⋯O, O—H⋯Br and C—H⋯O hydrogen bonds, complete a three-dimensional polymeric network formed between the methanol solvent and the complex.
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spelling pubmed-29600522010-12-30 Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate Schutte, Marietjie Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Re(C(7)H(2)Br(3)O(2))(CO)(3)(H(2)O)]·CH(3)OH, crystallized as a neutral Re(I) compound and one methanol solvent mol­ecule in the asymmetric unit. The metal centre is coordinated facially by three carbonyl groups. The bidentate tribromo­tropolanate ligand and a water mol­ecule complete the distorted octahedral coordination around the central metal. Inter­molecular Br⋯O [3.226 (5) Å] and Br⋯Br [3.590 (2) Å] contacts are observed between adjacent mol­ecules. These contacts, together with an array of O—H⋯O, O—H⋯Br and C—H⋯O hydrogen bonds, complete a three-dimensional polymeric network formed between the methanol solvent and the complex. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960052/ /pubmed/21581205 http://dx.doi.org/10.1107/S1600536808038737 Text en © Schutte et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schutte, Marietjie
Visser, Hendrik G.
Roodt, Andreas
Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate
title Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate
title_full Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate
title_fullStr Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate
title_full_unstemmed Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate
title_short Aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(I) methanol solvate
title_sort aqua­tricarbon­yl(3,5,7-tribromo­tropolonato)rhenium(i) methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960052/
https://www.ncbi.nlm.nih.gov/pubmed/21581205
http://dx.doi.org/10.1107/S1600536808038737
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AT visserhendrikg aquatricarbonyl357tribromotropolonatorheniumimethanolsolvate
AT roodtandreas aquatricarbonyl357tribromotropolonatorheniumimethanolsolvate

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