Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4)

In the title compound, [Cu(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·4C(3)H(7)NO, the Cu(II) ion is located on a crystallographic inversion center and is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms forming two long Cu—O bonds. One of the unique dimethyl­formami...

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Detalles Bibliográficos
Autores principales: Yun, Ruirui, Ying, Wei, Qi, Baoliang, Fan, Xuyang, Wu, Huilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960054/
https://www.ncbi.nlm.nih.gov/pubmed/21581145
http://dx.doi.org/10.1107/S1600536808036829
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author Yun, Ruirui
Ying, Wei
Qi, Baoliang
Fan, Xuyang
Wu, Huilu
author_facet Yun, Ruirui
Ying, Wei
Qi, Baoliang
Fan, Xuyang
Wu, Huilu
author_sort Yun, Ruirui
collection PubMed
description In the title compound, [Cu(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·4C(3)H(7)NO, the Cu(II) ion is located on a crystallographic inversion center and is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms forming two long Cu—O bonds. One of the unique dimethyl­formamide solvent mol­ecules is disordered over two sites with occupancies of 0.715 (6) and 0.285 (6). The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29600542010-12-30 Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4) Yun, Ruirui Ying, Wei Qi, Baoliang Fan, Xuyang Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(14)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·4C(3)H(7)NO, the Cu(II) ion is located on a crystallographic inversion center and is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms forming two long Cu—O bonds. One of the unique dimethyl­formamide solvent mol­ecules is disordered over two sites with occupancies of 0.715 (6) and 0.285 (6). The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960054/ /pubmed/21581145 http://dx.doi.org/10.1107/S1600536808036829 Text en © Yun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yun, Ruirui
Ying, Wei
Qi, Baoliang
Fan, Xuyang
Wu, Huilu
Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4)
title Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4)
title_full Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4)
title_fullStr Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4)
title_full_unstemmed Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4)
title_short Bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(II)–picrate–dimethyl­formamide (1/2/4)
title_sort bis[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]copper(ii)–picrate–dimethyl­formamide (1/2/4)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960054/
https://www.ncbi.nlm.nih.gov/pubmed/21581145
http://dx.doi.org/10.1107/S1600536808036829
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