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2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide
In the title compound, C(21)H(26)N(2)O, the dihedral angle between the two aromatic rings is 85.90 (19)°. The propenone–hydrazide unit forms dihedral angles of 21.62 (8) and 72.83 (9)°, respectively, with the terminal and central aromatic rings. The 2-methylpropyl group is disordered over two sites...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960058/ https://www.ncbi.nlm.nih.gov/pubmed/21581349 http://dx.doi.org/10.1107/S1600536808036817 |
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author | Fun, Hoong-Kun Jebas, Samuel Robinson Sujith, K. V. Kalluraya, B. |
author_facet | Fun, Hoong-Kun Jebas, Samuel Robinson Sujith, K. V. Kalluraya, B. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound, C(21)H(26)N(2)O, the dihedral angle between the two aromatic rings is 85.90 (19)°. The propenone–hydrazide unit forms dihedral angles of 21.62 (8) and 72.83 (9)°, respectively, with the terminal and central aromatic rings. The 2-methylpropyl group is disordered over two sites, with occupancies of 0.533 (13) and 0.467 (13). In crystal structure, molecules are linked into centrosymmetric dimers by paired N—H⋯O and C—H⋯O hydrogen bonds. In addition, C—H⋯π interactions are observed. |
format | Text |
id | pubmed-2960058 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29600582010-12-30 2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide Fun, Hoong-Kun Jebas, Samuel Robinson Sujith, K. V. Kalluraya, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(26)N(2)O, the dihedral angle between the two aromatic rings is 85.90 (19)°. The propenone–hydrazide unit forms dihedral angles of 21.62 (8) and 72.83 (9)°, respectively, with the terminal and central aromatic rings. The 2-methylpropyl group is disordered over two sites, with occupancies of 0.533 (13) and 0.467 (13). In crystal structure, molecules are linked into centrosymmetric dimers by paired N—H⋯O and C—H⋯O hydrogen bonds. In addition, C—H⋯π interactions are observed. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2960058/ /pubmed/21581349 http://dx.doi.org/10.1107/S1600536808036817 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Jebas, Samuel Robinson Sujith, K. V. Kalluraya, B. 2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide |
title | 2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide |
title_full | 2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide |
title_fullStr | 2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide |
title_full_unstemmed | 2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide |
title_short | 2-[4-(2-Methylpropyl)phenyl]-N′-[(E)-1-phenylethylidene]propanehydrazide |
title_sort | 2-[4-(2-methylpropyl)phenyl]-n′-[(e)-1-phenylethylidene]propanehydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960058/ https://www.ncbi.nlm.nih.gov/pubmed/21581349 http://dx.doi.org/10.1107/S1600536808036817 |
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