Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate

In the title compound, C(2)H(10)N(2) (2+)·2C(9)H(3)Br(4)O(4) (−)·CH(4)O, the N atoms of the ethane-1,2-diamine mol­ecule are protonated. The crystal structure is stabilized by N—H⋯O hydrogen bonds between the ethane-1,2-diaminium cations and 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)bromo­benzoate an...

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Autor principal: Liang, Zu-Pei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960063/
https://www.ncbi.nlm.nih.gov/pubmed/21581384
http://dx.doi.org/10.1107/S1600536808038166
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author Liang, Zu-Pei
author_facet Liang, Zu-Pei
author_sort Liang, Zu-Pei
collection PubMed
description In the title compound, C(2)H(10)N(2) (2+)·2C(9)H(3)Br(4)O(4) (−)·CH(4)O, the N atoms of the ethane-1,2-diamine mol­ecule are protonated. The crystal structure is stabilized by N—H⋯O hydrogen bonds between the ethane-1,2-diaminium cations and 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)bromo­benzoate anions, and by O—H⋯O and N—H⋯O hydrogen bonds between the methanol solvate and both the cation and the anion. In addition, the crystal structure exhibits a C—Br⋯O halogen bond [3.20 (3) Å] and a Br⋯Br inter­action [3.560 (2) Å].
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spelling pubmed-29600632010-12-30 Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate Liang, Zu-Pei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(2)H(10)N(2) (2+)·2C(9)H(3)Br(4)O(4) (−)·CH(4)O, the N atoms of the ethane-1,2-diamine mol­ecule are protonated. The crystal structure is stabilized by N—H⋯O hydrogen bonds between the ethane-1,2-diaminium cations and 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)bromo­benzoate anions, and by O—H⋯O and N—H⋯O hydrogen bonds between the methanol solvate and both the cation and the anion. In addition, the crystal structure exhibits a C—Br⋯O halogen bond [3.20 (3) Å] and a Br⋯Br inter­action [3.560 (2) Å]. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960063/ /pubmed/21581384 http://dx.doi.org/10.1107/S1600536808038166 Text en © Zu-Pei Liang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liang, Zu-Pei
Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate
title Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate
title_full Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate
title_fullStr Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate
title_full_unstemmed Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate
title_short Ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate
title_sort ethane-1,2-diaminium 3,4,5,6-tetra­bromo-2-(methoxy­carbon­yl)benzoate methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960063/
https://www.ncbi.nlm.nih.gov/pubmed/21581384
http://dx.doi.org/10.1107/S1600536808038166
work_keys_str_mv AT liangzupei ethane12diaminium3456tetrabromo2methoxycarbonylbenzoatemethanolsolvate

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