Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)

The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis­(ethyl­enedithio)tetra­thia­fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra­hedral [CoCl(4)](2−) anions. One of the BEDT-TTF mol­ecules is generate...

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Detalles Bibliográficos
Autores principales: Zhao, Fuqi, Li, Ping, Zhu, Xiaohui, Dong, Lihua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960064/
https://www.ncbi.nlm.nih.gov/pubmed/21581134
http://dx.doi.org/10.1107/S1600536808033692
Descripción
Sumario:The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis­(ethyl­enedithio)tetra­thia­fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra­hedral [CoCl(4)](2−) anions. One of the BEDT-TTF mol­ecules is generated by inversion. There are short S⋯S contacts between the stacks in the a direction and short C—H⋯Cl contacts between the radical cations and the anions.

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