Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)

The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis­(ethyl­enedithio)tetra­thia­fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra­hedral [CoCl(4)](2−) anions. One of the BEDT-TTF mol­ecules is generate...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Fuqi, Li, Ping, Zhu, Xiaohui, Dong, Lihua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960064/
https://www.ncbi.nlm.nih.gov/pubmed/21581134
http://dx.doi.org/10.1107/S1600536808033692
_version_ 1782188649876553728
author Zhao, Fuqi
Li, Ping
Zhu, Xiaohui
Dong, Lihua
author_facet Zhao, Fuqi
Li, Ping
Zhu, Xiaohui
Dong, Lihua
author_sort Zhao, Fuqi
collection PubMed
description The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis­(ethyl­enedithio)tetra­thia­fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra­hedral [CoCl(4)](2−) anions. One of the BEDT-TTF mol­ecules is generated by inversion. There are short S⋯S contacts between the stacks in the a direction and short C—H⋯Cl contacts between the radical cations and the anions.
format Text
id pubmed-2960064
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29600642010-12-30 Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2) Zhao, Fuqi Li, Ping Zhu, Xiaohui Dong, Lihua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis­(ethyl­enedithio)tetra­thia­fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra­hedral [CoCl(4)](2−) anions. One of the BEDT-TTF mol­ecules is generated by inversion. There are short S⋯S contacts between the stacks in the a direction and short C—H⋯Cl contacts between the radical cations and the anions. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960064/ /pubmed/21581134 http://dx.doi.org/10.1107/S1600536808033692 Text en © Zhao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Fuqi
Li, Ping
Zhu, Xiaohui
Dong, Lihua
Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)
title Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)
title_full Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)
title_fullStr Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)
title_full_unstemmed Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)
title_short Bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(II) (3/2)
title_sort bis(ethyl­enedithio)tetra­thia­fulvalenium–tetra­chloridocobaltate(ii) (3/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960064/
https://www.ncbi.nlm.nih.gov/pubmed/21581134
http://dx.doi.org/10.1107/S1600536808033692
work_keys_str_mv AT zhaofuqi bisethylenedithiotetrathiafulvaleniumtetrachloridocobaltateii32
AT liping bisethylenedithiotetrathiafulvaleniumtetrachloridocobaltateii32
AT zhuxiaohui bisethylenedithiotetrathiafulvaleniumtetrachloridocobaltateii32
AT donglihua bisethylenedithiotetrathiafulvaleniumtetrachloridocobaltateii32

Ejemplares similares