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Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate

The Ni atom in the title complex, [Ni(SO(4))(C(15)H(13)N(5))(H(2)O)]·H(2)O, has a distorted trigonal-bipyramidal coordination formed by the tridentate 2,6-bis­(2-pyridylamino)pyridine (tpdaH(2)) ligand, one sulfate and one coordinated water mol­ecule. The tpdaH(2) ligand is three-coordinated, with t...

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Detalles Bibliográficos
Autores principales: Lu, Lu, Wang, Jun, Xie, Bin, Zou, Li-Ke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960066/
https://www.ncbi.nlm.nih.gov/pubmed/21581113
http://dx.doi.org/10.1107/S1600536808035101
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author Lu, Lu
Wang, Jun
Xie, Bin
Zou, Li-Ke
author_facet Lu, Lu
Wang, Jun
Xie, Bin
Zou, Li-Ke
author_sort Lu, Lu
collection PubMed
description The Ni atom in the title complex, [Ni(SO(4))(C(15)H(13)N(5))(H(2)O)]·H(2)O, has a distorted trigonal-bipyramidal coordination formed by the tridentate 2,6-bis­(2-pyridylamino)pyridine (tpdaH(2)) ligand, one sulfate and one coordinated water mol­ecule. The tpdaH(2) ligand is three-coordinated, with the N atom of the central pyridine ring in the equatorial position [Ni—N = 1.9961 (14) Å] and the N atoms of the peripheral pyridine rings in the axial positions [Ni—N = 1.9668 (15) and 1.9895 (15) Å]. The remaining equatorial positions are occupied by the O atoms of the sulfate ligand and the water molecule. The H atoms of both NH groups of the tpdaH(2) ligand are involved in hydrogen bonds with the O atoms of the uncoordinated water mol­ecule and the sulfate group which link the complex mol­ecules, forming an infinite three-dimensional network.
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spelling pubmed-29600662010-12-30 Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate Lu, Lu Wang, Jun Xie, Bin Zou, Li-Ke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the title complex, [Ni(SO(4))(C(15)H(13)N(5))(H(2)O)]·H(2)O, has a distorted trigonal-bipyramidal coordination formed by the tridentate 2,6-bis­(2-pyridylamino)pyridine (tpdaH(2)) ligand, one sulfate and one coordinated water mol­ecule. The tpdaH(2) ligand is three-coordinated, with the N atom of the central pyridine ring in the equatorial position [Ni—N = 1.9961 (14) Å] and the N atoms of the peripheral pyridine rings in the axial positions [Ni—N = 1.9668 (15) and 1.9895 (15) Å]. The remaining equatorial positions are occupied by the O atoms of the sulfate ligand and the water molecule. The H atoms of both NH groups of the tpdaH(2) ligand are involved in hydrogen bonds with the O atoms of the uncoordinated water mol­ecule and the sulfate group which link the complex mol­ecules, forming an infinite three-dimensional network. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960066/ /pubmed/21581113 http://dx.doi.org/10.1107/S1600536808035101 Text en © Lu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lu, Lu
Wang, Jun
Xie, Bin
Zou, Li-Ke
Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate
title Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate
title_full Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate
title_fullStr Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate
title_full_unstemmed Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate
title_short Aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate
title_sort aqua­[2,6-bis­(2-pyridylamino)pyridine]sulfatonickel(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960066/
https://www.ncbi.nlm.nih.gov/pubmed/21581113
http://dx.doi.org/10.1107/S1600536808035101
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