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Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate
The Ni atom in the title complex, [Ni(SO(4))(C(15)H(13)N(5))(H(2)O)]·H(2)O, has a distorted trigonal-bipyramidal coordination formed by the tridentate 2,6-bis(2-pyridylamino)pyridine (tpdaH(2)) ligand, one sulfate and one coordinated water molecule. The tpdaH(2) ligand is three-coordinated, with t...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960066/ https://www.ncbi.nlm.nih.gov/pubmed/21581113 http://dx.doi.org/10.1107/S1600536808035101 |
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author | Lu, Lu Wang, Jun Xie, Bin Zou, Li-Ke |
author_facet | Lu, Lu Wang, Jun Xie, Bin Zou, Li-Ke |
author_sort | Lu, Lu |
collection | PubMed |
description | The Ni atom in the title complex, [Ni(SO(4))(C(15)H(13)N(5))(H(2)O)]·H(2)O, has a distorted trigonal-bipyramidal coordination formed by the tridentate 2,6-bis(2-pyridylamino)pyridine (tpdaH(2)) ligand, one sulfate and one coordinated water molecule. The tpdaH(2) ligand is three-coordinated, with the N atom of the central pyridine ring in the equatorial position [Ni—N = 1.9961 (14) Å] and the N atoms of the peripheral pyridine rings in the axial positions [Ni—N = 1.9668 (15) and 1.9895 (15) Å]. The remaining equatorial positions are occupied by the O atoms of the sulfate ligand and the water molecule. The H atoms of both NH groups of the tpdaH(2) ligand are involved in hydrogen bonds with the O atoms of the uncoordinated water molecule and the sulfate group which link the complex molecules, forming an infinite three-dimensional network. |
format | Text |
id | pubmed-2960066 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29600662010-12-30 Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate Lu, Lu Wang, Jun Xie, Bin Zou, Li-Ke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the title complex, [Ni(SO(4))(C(15)H(13)N(5))(H(2)O)]·H(2)O, has a distorted trigonal-bipyramidal coordination formed by the tridentate 2,6-bis(2-pyridylamino)pyridine (tpdaH(2)) ligand, one sulfate and one coordinated water molecule. The tpdaH(2) ligand is three-coordinated, with the N atom of the central pyridine ring in the equatorial position [Ni—N = 1.9961 (14) Å] and the N atoms of the peripheral pyridine rings in the axial positions [Ni—N = 1.9668 (15) and 1.9895 (15) Å]. The remaining equatorial positions are occupied by the O atoms of the sulfate ligand and the water molecule. The H atoms of both NH groups of the tpdaH(2) ligand are involved in hydrogen bonds with the O atoms of the uncoordinated water molecule and the sulfate group which link the complex molecules, forming an infinite three-dimensional network. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960066/ /pubmed/21581113 http://dx.doi.org/10.1107/S1600536808035101 Text en © Lu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lu, Lu Wang, Jun Xie, Bin Zou, Li-Ke Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate |
title | Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate |
title_full | Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate |
title_fullStr | Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate |
title_full_unstemmed | Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate |
title_short | Aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(II) monohydrate |
title_sort | aqua[2,6-bis(2-pyridylamino)pyridine]sulfatonickel(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960066/ https://www.ncbi.nlm.nih.gov/pubmed/21581113 http://dx.doi.org/10.1107/S1600536808035101 |
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