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[1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate

In the title compound, [FeRu(C(17)H(14)P)(2)(C(6)H(8)BN(4))H(CO)]·C(3)H(6)O, the Ru(II) ion is coordinated in a distorted octa­hedral environment involving a hydride ligand, a carbonyl ligand and two bidentate ligands. Of the two bidentate ligands, the bulky 1,1′-bis­(diphenyl­phosphino)ferrocene (d...

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Autores principales: Huh, Seong, Lough, Alan J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960072/
https://www.ncbi.nlm.nih.gov/pubmed/21581157
http://dx.doi.org/10.1107/S1600536808037100
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author Huh, Seong
Lough, Alan J.
author_facet Huh, Seong
Lough, Alan J.
author_sort Huh, Seong
collection PubMed
description In the title compound, [FeRu(C(17)H(14)P)(2)(C(6)H(8)BN(4))H(CO)]·C(3)H(6)O, the Ru(II) ion is coordinated in a distorted octa­hedral environment involving a hydride ligand, a carbonyl ligand and two bidentate ligands. Of the two bidentate ligands, the bulky 1,1′-bis­(diphenyl­phosphino)ferrocene (dppf) ligand chelates with a larger bite angle of 101.90 (2)°, whereas the bite angle of the [H(2)Bpz(2)](−) ligand (pz = pyrazol­yl) is 85.67 (7)°. The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand. The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand. In the crystal structure, there are weak inter­molecular C—H⋯O hydrogen bonds between complex mol­ecules and acetone solvent mol­ecules.
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spelling pubmed-29600722010-12-30 [1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate Huh, Seong Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [FeRu(C(17)H(14)P)(2)(C(6)H(8)BN(4))H(CO)]·C(3)H(6)O, the Ru(II) ion is coordinated in a distorted octa­hedral environment involving a hydride ligand, a carbonyl ligand and two bidentate ligands. Of the two bidentate ligands, the bulky 1,1′-bis­(diphenyl­phosphino)ferrocene (dppf) ligand chelates with a larger bite angle of 101.90 (2)°, whereas the bite angle of the [H(2)Bpz(2)](−) ligand (pz = pyrazol­yl) is 85.67 (7)°. The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand. The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand. In the crystal structure, there are weak inter­molecular C—H⋯O hydrogen bonds between complex mol­ecules and acetone solvent mol­ecules. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960072/ /pubmed/21581157 http://dx.doi.org/10.1107/S1600536808037100 Text en © Huh and Lough 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huh, Seong
Lough, Alan J.
[1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate
title [1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate
title_full [1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate
title_fullStr [1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate
title_full_unstemmed [1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate
title_short [1,1′-Bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate
title_sort [1,1′-bis(diphenyl­phosphino)ferrocene]carbon­yl[dihydro­bis(pyrazol-1-yl)borato]hydridoruthenium(ii) acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960072/
https://www.ncbi.nlm.nih.gov/pubmed/21581157
http://dx.doi.org/10.1107/S1600536808037100
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